Time-Resolved FTIR Study on the Reaction of CHCl2 with NO2
文献类型：期刊论文
| 作者 | Liu, Kun-hui; Yang, Chun-fan; Wang, Huan; Wu, Wei-qiang; Su, Hong-mei |
| 刊名 | CHINESE JOURNAL OF CHEMICAL PHYSICS
 |
| 出版日期 | 2009-04-01 |
| 卷号 | 22期号:2页码:134-138 |
| 关键词 | Tr-ftir Dichloromethyl No2 Reaction Product Channel |
| ISSN号 | 1674-0068 |
| DOI | 10.1088/1674-0068/22/02/134-138 |
| 英文摘要 | The environmentally important free radical reaction of chlorinated methyl CHCl2 with NO2 was investigated by step-scan time-resolved FTIR (TR-FTIR) emission spectroscopy. Vibrationally excited products of CHClO, NO, CO, and HCl are observed in the high-resolution IR emission spectra and three possible reaction channels are therefore elucidated. In particular, the product CO is newly detected and the product HCl is identified explicitly as a yield from the CHCl2+NO2 reaction, taking advantage of the sensitive detection of HCl and CO with TR-FTIR. These results are of particular interests to understand the related realistic chemical processes including atmospheric photochemistry, biofuel combustion, waste destruction, and smoking fire. |
| 语种 | 英语 |
| WOS记录号 | WOS:000265896000006 |
| 出版者 | CHINESE PHYSICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66141]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Su, Hong-mei |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Kun-hui,Yang, Chun-fan,Wang, Huan,et al. Time-Resolved FTIR Study on the Reaction of CHCl2 with NO2[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2009,22(2):134-138. |
| APA | Liu, Kun-hui,Yang, Chun-fan,Wang, Huan,Wu, Wei-qiang,&Su, Hong-mei.(2009).Time-Resolved FTIR Study on the Reaction of CHCl2 with NO2.CHINESE JOURNAL OF CHEMICAL PHYSICS,22(2),134-138. |
| MLA | Liu, Kun-hui,et al."Time-Resolved FTIR Study on the Reaction of CHCl2 with NO2".CHINESE JOURNAL OF CHEMICAL PHYSICS 22.2(2009):134-138. |
入库方式： OAI收割
来源：化学研究所
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