A Self-Assembled 3D Hydrogen Bonded Network Constructed from Polyoxovanadate and Protonated Organic Substrate With a Solvent Hydrolysis Reaction
文献类型：期刊论文
| 作者 | Yan, Jie1; Zhao, Haiyan1; Li, Zhangpeng1; Xing, Yongheng1; Zeng, Xiaoqing2; Ge, Maofa2; Niu, Shuyun1 |
| 刊名 | JOURNAL OF CLUSTER SCIENCE
 |
| 出版日期 | 2009-12-01 |
| 卷号 | 20期号:4页码:717-724 |
| 关键词 | Polyoxovanadate Hydrogen Bond Crystal Structure Topology |
| ISSN号 | 1040-7278 |
| DOI | 10.1007/s10876-009-0274-1 |
| 英文摘要 | A self-assembled 3D hydrogen bonded network constructed from polyoxovanadate and organic substrate [V10O28][(CH3)(2)NH2](4)(imidazolium)(2) (1) has been synthesized at room temperature and characterized by elemental analysis, IR and single-crystal X-ray diffraction. The structure of 1 can be regarded as being linked by the dimethylammonium cations of the decavanadate clusters to produce an interesting 3D network with a 4(12)6(3) topology. In the resulting network, there exist one-dimensional channels along the a-axis, in which the imidazolium cations filled the channels. These imidazolium cations are involved in intermolecular hydrogen bonds of the types N-H center dot center dot center dot O and C-H center dot center dot center dot O, which seem to be main forces to stabilize the holistic structure. |
| 语种 | 英语 |
| WOS记录号 | WOS:000272616700008 |
| 出版者 | SPRINGER/PLENUM PUBLISHERS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66169]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xing, Yongheng |
| 作者单位 | 1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yan, Jie,Zhao, Haiyan,Li, Zhangpeng,et al. A Self-Assembled 3D Hydrogen Bonded Network Constructed from Polyoxovanadate and Protonated Organic Substrate With a Solvent Hydrolysis Reaction[J]. JOURNAL OF CLUSTER SCIENCE,2009,20(4):717-724. |
| APA | Yan, Jie.,Zhao, Haiyan.,Li, Zhangpeng.,Xing, Yongheng.,Zeng, Xiaoqing.,...&Niu, Shuyun.(2009).A Self-Assembled 3D Hydrogen Bonded Network Constructed from Polyoxovanadate and Protonated Organic Substrate With a Solvent Hydrolysis Reaction.JOURNAL OF CLUSTER SCIENCE,20(4),717-724. |
| MLA | Yan, Jie,et al."A Self-Assembled 3D Hydrogen Bonded Network Constructed from Polyoxovanadate and Protonated Organic Substrate With a Solvent Hydrolysis Reaction".JOURNAL OF CLUSTER SCIENCE 20.4(2009):717-724. |
入库方式： OAI收割
来源：化学研究所
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