Synthesis of Aromatic Oxide-Oxadiazoles Containing Pyridine Ring and Study on Their Spectral Properties
文献类型：期刊论文
| 作者 | Ren Xinjuan1; Wang Lei1; Gao Lei1; Xie Zhiyuan2; Li Dongfeng1 |
| 刊名 | CHINESE JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2009-07-01 |
| 卷号 | 29期号:7页码:1147-1151 |
| 关键词 | Pyridine Aromatic Oxide-oxadiazole Fluorescence Quantum Yield Synthesis Fluorescence Spectrum |
| ISSN号 | 0253-2786 |
| 英文摘要 | In order to explore new highly organic electroluminescent materials, six symmetrical aromatic oxide-oxadiazoles containing pyridine ring 4a similar to 4f were synthesized through cyclization of substituted benzoic acid (2) with 2,6-dihydrazide pyridine (3) by "one-pot" method in POCl(3). Their structures were confirmed by MS, IR, (1)H NMR techniques and elemental analysis. The fluorescence spectra of the target compounds showed that the A,m ranged from 347 to 507 nm, and the maximum A,m were close to 384 nm, which showed that these compounds have good fluorescence with strong fluorescence intensity. When the 5-Br group was introduced into the aromatic ring (4e and 4f), the fluorescent emission wavelength took place Einstein shift, and the fluorescent intensity decreased a little. Using quinine bisulphate as a reference, the fluorescence quantum yields were all tested, and the introduction of 5-Br group had no visible effect on fluorescence quantum yield. The fluorescence quantum yields of representative 4a in different solvents at maximum excitation wavelength were also measured and the results showed that the polarity of the solvents hardly had any relation to the fluorescence quantum yields of the target compounds. |
| 语种 | 英语 |
| WOS记录号 | WOS:000268736000018 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66183]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ren Xinjuan |
| 作者单位 | 1.Changchun Univ Technol, Sch Chem & Lifie Sci, Changchun 30012, Peoples R China 2.Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ren Xinjuan,Wang Lei,Gao Lei,et al. Synthesis of Aromatic Oxide-Oxadiazoles Containing Pyridine Ring and Study on Their Spectral Properties[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2009,29(7):1147-1151. |
| APA | Ren Xinjuan,Wang Lei,Gao Lei,Xie Zhiyuan,&Li Dongfeng.(2009).Synthesis of Aromatic Oxide-Oxadiazoles Containing Pyridine Ring and Study on Their Spectral Properties.CHINESE JOURNAL OF ORGANIC CHEMISTRY,29(7),1147-1151. |
| MLA | Ren Xinjuan,et al."Synthesis of Aromatic Oxide-Oxadiazoles Containing Pyridine Ring and Study on Their Spectral Properties".CHINESE JOURNAL OF ORGANIC CHEMISTRY 29.7(2009):1147-1151. |
入库方式： OAI收割
来源：化学研究所
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