Synthesis, structure and superoxide dismutase activity of two self-assembly transition metal complexes containing a tridentate amino-Schiff base deviating from salicylaldehyde with glycine
文献类型：期刊论文
| 作者 | Han Jing1; Bai FengYing1; Zhao HaiYan1; Xing YongHeng1; Zeng XiaoQing2; Ge MaoFa2 |
| 刊名 | CHINESE SCIENCE BULLETIN
 |
| 出版日期 | 2009-10-01 |
| 卷号 | 54期号:19页码:3508-3514 |
| 关键词 | Salicylideneglycine Ligand Complexes Crystal Structure Superoxide Dismutase |
| ISSN号 | 1001-6538 |
| DOI | 10.1007/s11434-009-0449-z |
| 英文摘要 | Two new transition metal (Cu, Ni) complexes with amino-Schiff base ligand, (C9H7NO3)Cu(C14H12N2)center dot H2O (1) and (C9H7NO3)Ni(C3H4N2)(3)center dot H2O (2), have been designed and synthesized in ethanol solution at room temperature. Both of the complexes have been characterized by elemental analysis, IR spectra, UV-vis spectroscopy and X-ray single crystal diffraction. For complex 1, the coordination environment of the central copper atom is a distorted square pyramid, and one-dimensional chain is formed through the inter-molecular hydrogen bonds (O4-H2Wa <-O3, O4-H2Wa <-O3(#1) (#1: -x+1, y, -z+3/2)) and weak interactions (pi-pi stacking interaction) between the phenyl rings. For complex 2, the nickel atom is 6-coordinated and in a distorted octahedral environment, and a discrete hydrogen-bond cluster (four molecules are connected by hydrogen bonds into a group) is formed via two types of intra-molecular hydrogen bonds (O-Ha <-O, N-Ha <-O) and inter-molecular hydrogen bonds (O-Ha <-O, N-Ha <-O). |
| 语种 | 英语 |
| WOS记录号 | WOS:000271025500017 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66203]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xing YongHeng |
| 作者单位 | 1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Han Jing,Bai FengYing,Zhao HaiYan,et al. Synthesis, structure and superoxide dismutase activity of two self-assembly transition metal complexes containing a tridentate amino-Schiff base deviating from salicylaldehyde with glycine[J]. CHINESE SCIENCE BULLETIN,2009,54(19):3508-3514. |
| APA | Han Jing,Bai FengYing,Zhao HaiYan,Xing YongHeng,Zeng XiaoQing,&Ge MaoFa.(2009).Synthesis, structure and superoxide dismutase activity of two self-assembly transition metal complexes containing a tridentate amino-Schiff base deviating from salicylaldehyde with glycine.CHINESE SCIENCE BULLETIN,54(19),3508-3514. |
| MLA | Han Jing,et al."Synthesis, structure and superoxide dismutase activity of two self-assembly transition metal complexes containing a tridentate amino-Schiff base deviating from salicylaldehyde with glycine".CHINESE SCIENCE BULLETIN 54.19(2009):3508-3514. |
入库方式： OAI收割
来源：化学研究所
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