Selective Phenol Hydrogenation to Cyclohexanone Over a Dual Supported Pd-Lewis Acid Catalyst
文献类型：期刊论文
| 作者 | Liu, Huizhen; Jiang, Tao; Han, Buxing; Liang, Shuguang; Zhou, Yinxi |
| 刊名 | SCIENCE
 |
| 出版日期 | 2009-11-27 |
| 卷号 | 326期号:5957页码:1250-1252 |
| ISSN号 | 0036-8075 |
| DOI | 10.1126/science.1179713 |
| 英文摘要 | Cyclohexanone is an industrially important intermediate in the synthesis of materials such as nylon, but preparing it efficiently through direct hydrogenation of phenol is hindered by over-reduction to cyclohexanol. Here we report that a previously unappreciated combination of two common commercial catalysts. nanoparticulate palladium (supported on carbon, alumina, or NaY zeolite) and a Lewis acid such as AlCl(3-)synergistically promotes this reaction. Conversion exceeding 99.9% was achieved with >99.9% selectivity within 7 hours at 1.0-megapascal hydrogen pressure and 50 degrees C. The reaction was accelerated at higher temperature or in a compressed CO(2) solvent medium. Preliminary kinetic and spectroscopic studies suggest that the Lewis acid sequentially enhances the hydrogenation of phenol to cyclohexanone and then inhibits further hydrogenation of the ketone. |
| 语种 | 英语 |
| WOS记录号 | WOS:000272117900044 |
| 出版者 | AMER ASSOC ADVANCEMENT SCIENCE |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66237]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang, Tao |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Huizhen,Jiang, Tao,Han, Buxing,et al. Selective Phenol Hydrogenation to Cyclohexanone Over a Dual Supported Pd-Lewis Acid Catalyst[J]. SCIENCE,2009,326(5957):1250-1252. |
| APA | Liu, Huizhen,Jiang, Tao,Han, Buxing,Liang, Shuguang,&Zhou, Yinxi.(2009).Selective Phenol Hydrogenation to Cyclohexanone Over a Dual Supported Pd-Lewis Acid Catalyst.SCIENCE,326(5957),1250-1252. |
| MLA | Liu, Huizhen,et al."Selective Phenol Hydrogenation to Cyclohexanone Over a Dual Supported Pd-Lewis Acid Catalyst".SCIENCE 326.5957(2009):1250-1252. |
入库方式： OAI收割
来源：化学研究所
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