A Novel Strategy to Branched Polyacrylonitrile Via One-Pot RAFT Copolymerization of Acrylonitrile and an Asymmetrical Divinyl Monomer
文献类型：期刊论文
| 作者 | Liu, Xiao-Hui; Zhang, Gui-Bao; Li, Bai-Xiang; Bai, Yun-Gang |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2009-10-05 |
| 卷号 | 114期号:1页码:663-670 |
| 关键词 | Reversible Addition-fragmentation Chain Transfer (Raft) Branched Polymer Acrylonitrile Allyl Methacrylate |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.30599 |
| 英文摘要 | Branched polyacrylonitriles were prepared via the one-pot radical copolymerization of acrylonitirle and an asymmetric divinyl monomer (allyl methacrylate) that possesses both a higher reactive methacrylate and a lower reactive allyl. RAFT technique was used to keep a low-propagation chain concentration via a fast reversible chain transfer euilibration and thus the cross-linking was prevented until a high level of monomer conversions. This novel strategy was demonstrated to engenerate a branched architecture with abundant pendant functional vinyl and nitrile groups, and controlled molecular weight as a behavior of controlled/living radical polymerization characteristics. The effect of the various experimental parameters, including temperature, brancher to monomer molar ratio, and chain transfer agent to initiator molar ratio, on the control Of moleculer dimension (molecular weight and polydispersity indices) and the degree of branching were investigated in detail. Moreover, (1)H NMR and gel permeation chromatography confirm the branched architecture of the resultant polymer. The intrinsic viscosity of the copolymer is also lower than the linear counterpart. (C) 2009 Wiley Periodicals, Inc. J Appl Polyni Sci 114: 663-670, 2009 |
| 语种 | 英语 |
| WOS记录号 | WOS:000268738500079 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66253]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Xiao-Hui |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Jilin, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xiao-Hui,Zhang, Gui-Bao,Li, Bai-Xiang,et al. A Novel Strategy to Branched Polyacrylonitrile Via One-Pot RAFT Copolymerization of Acrylonitrile and an Asymmetrical Divinyl Monomer[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2009,114(1):663-670. |
| APA | Liu, Xiao-Hui,Zhang, Gui-Bao,Li, Bai-Xiang,&Bai, Yun-Gang.(2009).A Novel Strategy to Branched Polyacrylonitrile Via One-Pot RAFT Copolymerization of Acrylonitrile and an Asymmetrical Divinyl Monomer.JOURNAL OF APPLIED POLYMER SCIENCE,114(1),663-670. |
| MLA | Liu, Xiao-Hui,et al."A Novel Strategy to Branched Polyacrylonitrile Via One-Pot RAFT Copolymerization of Acrylonitrile and an Asymmetrical Divinyl Monomer".JOURNAL OF APPLIED POLYMER SCIENCE 114.1(2009):663-670. |
入库方式： OAI收割
来源：化学研究所
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