Synthesis and Properties of Monomer Casting Polyamide 6/Poly(methyl methacrylate) Blends
文献类型：期刊论文
| 作者 | Wu, Tongfei1,2; Xie, Tingxiu3; Yang, Guisheng1,3 |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2009-01-05 |
| 卷号 | 111期号:1页码:101-107 |
| 关键词 | Blends Compatibility Crystallization |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.29014 |
| 英文摘要 | We successfully synthesized monomer casting polyamide 6 (MCPA6)/poly(methyl methacrylate) (PMMA) blends in two steps: (1) radical polymerization of methyl methacrylate in epsilon-caprolactam and (2) anionic ring-opening polymerization of this epsilon-caprolactam solution. The influence of PMMA on the crystallization behavior of MCPA6 was studied with differential scanning calorimetry and X-ray diffraction, which showed that PMMA could act as a heterogeneous nucleation agent and favored the formation of the gamma-crystalline form. The rheological properties were also studied and indicated that PMMA reduced the interaction between MCPA6 chains by lowering the density of hydrogen bonding. This study used a novel and convenient method to prepare microporous MCPA6/PMMA particles that involved removing the continuous phase. Their surface area and thermal stability were characterized by the Brunauer-Emmett-Teller method and thermogravimetric analysis, respectively. (C) 2008 Wiley Periodicals, Inc. J Appl Polym Sci 111: 101-107, 2009 |
| 语种 | 英语 |
| WOS记录号 | WOS:000261152400013 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66265]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Guisheng |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Technol, Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China 3.Shanghai Genius Adv Mat Co Ltd, Shanghai 201109, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Tongfei,Xie, Tingxiu,Yang, Guisheng. Synthesis and Properties of Monomer Casting Polyamide 6/Poly(methyl methacrylate) Blends[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2009,111(1):101-107. |
| APA | Wu, Tongfei,Xie, Tingxiu,&Yang, Guisheng.(2009).Synthesis and Properties of Monomer Casting Polyamide 6/Poly(methyl methacrylate) Blends.JOURNAL OF APPLIED POLYMER SCIENCE,111(1),101-107. |
| MLA | Wu, Tongfei,et al."Synthesis and Properties of Monomer Casting Polyamide 6/Poly(methyl methacrylate) Blends".JOURNAL OF APPLIED POLYMER SCIENCE 111.1(2009):101-107. |
入库方式： OAI收割
来源：化学研究所
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