中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Thermo- and pH-Responsive Dendronized Copolymers of Styrene and Maleic Anhydride Pendant with Poly(amidoamine) Dendrons as Side Groups

文献类型:期刊论文

作者Gao, Min1; Jia, Xinru1; Kuang, Guichao1; Li, Yan1; Liang, Dehai1; Wei, Yen2
刊名MACROMOLECULES
出版日期2009-06-23
卷号42期号:12页码:4273-4281
ISSN号0024-9297
DOI10.1021/ma900085j
英文摘要A series of thermo- and pH-dual responsive dendronized polymers PSADG1-PSADG3 were successfully synthesized by attaching butylamide terminated poly(amidoamine) dendrons (DG1-DG3) to the alternating copolymers of styrene (St) and maleic anhydride (MAh). The structures and the molecular weights of the obtained polymers were characterized by (1)H NMR and FTIR. The coverage degrees of DG(1)-DG(3) dendrons were 83.5%, 64.9%, and 60.5%, respectively, indicating that the numbers of the attaching dendrons decreased in the order of G1 > G2 > G3. The turbidity measurements revealed that all the dendronized polymers exhibited reversible thermo-responsive property in deionized water, and the LCST values increased from PSADG1 to PSADG3 due to both the coverage degree and the structure of dendrons. Moreover, these dendronized polymers were sensitive to pH oil account of the carboxylic and tertiary amino groups in the architecture. It hits been found that, for example, the PSADG2 did not display thermal sensitivity in acidic environment (pH 2.4), whereas the phase transition occurred in near neutral (pH 6.0) and basic conditions (pH 10.6) with the LCST of 33.1 and 49.0 degrees C, respectively. It was also found that, at pH 6.0, the polymers formed larger aggregates with R(h,app) of ca. 0.6 mu m at elevated temperatures mainly because of the dehydration and the enhanced hydrophobic interactions. The morphology of the aggregates was monitored by optical microscopy, and uniform spherical aggregates with it diameter of 5-10 mu m were observed above the LCST.
语种英语
WOS记录号WOS:000267048200064
出版者AMER CHEMICAL SOC
源URL[http://ir.iccas.ac.cn/handle/121111/66299]  
专题中国科学院化学研究所
通讯作者Jia, Xinru
作者单位1.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Polymer Chem & Phys, Coll Chem & Mol Engn,Minist Educ, Beijing 100871, Peoples R China
2.Drexel Univ, Dept Chem, Philadelphia, PA 19104 USA
推荐引用方式
GB/T 7714
Gao, Min,Jia, Xinru,Kuang, Guichao,et al. Thermo- and pH-Responsive Dendronized Copolymers of Styrene and Maleic Anhydride Pendant with Poly(amidoamine) Dendrons as Side Groups[J]. MACROMOLECULES,2009,42(12):4273-4281.
APA Gao, Min,Jia, Xinru,Kuang, Guichao,Li, Yan,Liang, Dehai,&Wei, Yen.(2009).Thermo- and pH-Responsive Dendronized Copolymers of Styrene and Maleic Anhydride Pendant with Poly(amidoamine) Dendrons as Side Groups.MACROMOLECULES,42(12),4273-4281.
MLA Gao, Min,et al."Thermo- and pH-Responsive Dendronized Copolymers of Styrene and Maleic Anhydride Pendant with Poly(amidoamine) Dendrons as Side Groups".MACROMOLECULES 42.12(2009):4273-4281.

入库方式: OAI收割

来源:化学研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。