Polymer-Assisted Crystallization and Optical Properties of Uniform Microrods of Organic Dye Sudan II
文献类型:期刊论文
作者 | Yu, Han; Qi, Limin |
刊名 | LANGMUIR
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出版日期 | 2009-06-16 |
卷号 | 25期号:12页码:6781-6786 |
ISSN号 | 0743-7463 |
DOI | 10.1021/la900296y |
英文摘要 | The self-assembly of uniform single-crystal line microrods of organic dye Sudan II (1-(2,4-dimethylphenylazo)-2-naphthol) in solution was achieved by reprecipitation with the assistance of amphiphilic block copolymer Pluronic F127. It was found that the formation of F127 micelles was favorable for the production or uniform Sudan II microrods whereas individual F127 molecules favored the formation of Sudan II fibers. The optical absorption and fluorescence emission properties of the uniform microrods were characterized, and the time-dependent spectra of the precipitating solution for microrod formation were measured to monitor the self-assembly process of Sudan II molecules. The Sudan II microrods exhibited intense fluorescence emission, indicating an unusual aggregation-induced emission (AIE) phenomenon for Sudan II. The fluorescent microscopy investigation suggested that the obtained Sudan II microrods exhibited remarkable optical waveguide behavior, which is expected to serve as single rod active optical waveguides that can be used as building blocks for miniaturized photonic devices. Furthermore, novel Sudan II microplates, which exhibited interesting 2D optical waveguide behavior, were readily obtained by reprecipitation of Sudan II from cationic surfactant cetyltrimethylammonium bromide (CTAB) solution. |
语种 | 英语 |
WOS记录号 | WOS:000266929900030 |
出版者 | AMER CHEMICAL SOC |
源URL | [http://ir.iccas.ac.cn/handle/121111/66339] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Qi, Limin |
作者单位 | Peking Univ, Coll Chem, State Key Lab Struct Chem Unstable & Stable Speci, BNLMS, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Yu, Han,Qi, Limin. Polymer-Assisted Crystallization and Optical Properties of Uniform Microrods of Organic Dye Sudan II[J]. LANGMUIR,2009,25(12):6781-6786. |
APA | Yu, Han,&Qi, Limin.(2009).Polymer-Assisted Crystallization and Optical Properties of Uniform Microrods of Organic Dye Sudan II.LANGMUIR,25(12),6781-6786. |
MLA | Yu, Han,et al."Polymer-Assisted Crystallization and Optical Properties of Uniform Microrods of Organic Dye Sudan II".LANGMUIR 25.12(2009):6781-6786. |
入库方式: OAI收割
来源:化学研究所
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