中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Polymer-Assisted Crystallization and Optical Properties of Uniform Microrods of Organic Dye Sudan II

文献类型:期刊论文

作者Yu, Han; Qi, Limin
刊名LANGMUIR
出版日期2009-06-16
卷号25期号:12页码:6781-6786
ISSN号0743-7463
DOI10.1021/la900296y
英文摘要The self-assembly of uniform single-crystal line microrods of organic dye Sudan II (1-(2,4-dimethylphenylazo)-2-naphthol) in solution was achieved by reprecipitation with the assistance of amphiphilic block copolymer Pluronic F127. It was found that the formation of F127 micelles was favorable for the production or uniform Sudan II microrods whereas individual F127 molecules favored the formation of Sudan II fibers. The optical absorption and fluorescence emission properties of the uniform microrods were characterized, and the time-dependent spectra of the precipitating solution for microrod formation were measured to monitor the self-assembly process of Sudan II molecules. The Sudan II microrods exhibited intense fluorescence emission, indicating an unusual aggregation-induced emission (AIE) phenomenon for Sudan II. The fluorescent microscopy investigation suggested that the obtained Sudan II microrods exhibited remarkable optical waveguide behavior, which is expected to serve as single rod active optical waveguides that can be used as building blocks for miniaturized photonic devices. Furthermore, novel Sudan II microplates, which exhibited interesting 2D optical waveguide behavior, were readily obtained by reprecipitation of Sudan II from cationic surfactant cetyltrimethylammonium bromide (CTAB) solution.
语种英语
WOS记录号WOS:000266929900030
出版者AMER CHEMICAL SOC
源URL[http://ir.iccas.ac.cn/handle/121111/66339]  
专题中国科学院化学研究所
通讯作者Qi, Limin
作者单位Peking Univ, Coll Chem, State Key Lab Struct Chem Unstable & Stable Speci, BNLMS, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Yu, Han,Qi, Limin. Polymer-Assisted Crystallization and Optical Properties of Uniform Microrods of Organic Dye Sudan II[J]. LANGMUIR,2009,25(12):6781-6786.
APA Yu, Han,&Qi, Limin.(2009).Polymer-Assisted Crystallization and Optical Properties of Uniform Microrods of Organic Dye Sudan II.LANGMUIR,25(12),6781-6786.
MLA Yu, Han,et al."Polymer-Assisted Crystallization and Optical Properties of Uniform Microrods of Organic Dye Sudan II".LANGMUIR 25.12(2009):6781-6786.

入库方式: OAI收割

来源:化学研究所

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