Highly efficient phosphorescent iridium (III) diazine complexes for OLEDs: Different photophysical property between iridium (III) pyrazine complex and iridium (III) pyrimidine complex
文献类型：期刊论文
| 作者 | Ge, Guoping1; He, Jing2; Guo, Haiqing1; Wang, Fuzhi3; Zou, Dechun3 |
| 刊名 | JOURNAL OF ORGANOMETALLIC CHEMISTRY
 |
| 出版日期 | 2009-09-01 |
| 卷号 | 694期号:19页码:3050-3057 |
| 关键词 | Phosphorescence Iridium Diazine Complex (3)Mlct Oled |
| ISSN号 | 0022-328X |
| DOI | 10.1016/j.jorganchem.2009.05.037 |
| 英文摘要 | The synthesis and luminescence of four new iridium (III) diazine complexes (1-4) were investigated. HOMO and LUMO energy levels of the complexes were estimated according to the electrochemical performance and the UV-Vis absorption spectra, showing the pyrimidine complexes have a larger increase for the LUMO than the HOMO orbital in comparison with the pyrazine complexes. Several high-efficiency yellow and green OLEDs based on phosphorescent iridium (III) diazine complexes were obtained. The devices emitting yellow light based on 1 with turn-on voltage of 4.1 V exhibited an external quantum efficiency of 13.2% (power efficiency 20.3 lm/W), a maximum current efficiency of 37.3 cd/A. The electroluminescent performance for the green iridium pyrimidine complex of 3 is comparable to that of the iridium pyridine complex (PPY)(2)Ir(acac) (PPY = 2-phenylpyridine), which is among the best reported. (C) 2009 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000268799500002 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66341]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Guo, Haiqing |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Beijing Forestry Univ, Coll Mat Sci & Technol, Beijing 100083, Peoples R China 3.Peking Univ, Key Lab Polymer Chem & Phys, Educ Minist, Dept Polymer Sci & Engn,Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ge, Guoping,He, Jing,Guo, Haiqing,et al. Highly efficient phosphorescent iridium (III) diazine complexes for OLEDs: Different photophysical property between iridium (III) pyrazine complex and iridium (III) pyrimidine complex[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2009,694(19):3050-3057. |
| APA | Ge, Guoping,He, Jing,Guo, Haiqing,Wang, Fuzhi,&Zou, Dechun.(2009).Highly efficient phosphorescent iridium (III) diazine complexes for OLEDs: Different photophysical property between iridium (III) pyrazine complex and iridium (III) pyrimidine complex.JOURNAL OF ORGANOMETALLIC CHEMISTRY,694(19),3050-3057. |
| MLA | Ge, Guoping,et al."Highly efficient phosphorescent iridium (III) diazine complexes for OLEDs: Different photophysical property between iridium (III) pyrazine complex and iridium (III) pyrimidine complex".JOURNAL OF ORGANOMETALLIC CHEMISTRY 694.19(2009):3050-3057. |
入库方式： OAI收割
来源：化学研究所
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