Lanthanide-alkali metals-oxalates coordination polymers: Synthesis and structures of [Nd(C2O4)(1.5)(H2O)(3)] center dot 2H(2)O, Nd(C2O4)(CH3COO)(H2O), KLn(C2O4)(2)(H2O)(4) (Ln = Y, Tb)
文献类型：期刊论文
| 作者 | Zhang, Xingjing1; Xing, Yongheng1; Wang, Chunguang1; Han, Jing1; Li, Jing1; Ge, Maofa2; Zeng, Xiaoqing2; Niu, Shuyun1 |
| 刊名 | INORGANICA CHIMICA ACTA
 |
| 出版日期 | 2009-03-02 |
| 卷号 | 362期号:4页码:1058-1064 |
| 关键词 | Lanthanide Oxalate Synthesis Structure Spectrum |
| ISSN号 | 0020-1693 |
| DOI | 10.1016/j.ica.2008.05.029 |
| 英文摘要 | Two new lanthanide-oxalates coordination polymers, [Nd(C2O4)(1.5)(H2O)(3)] center dot 2H(2)O 1, Nd(C2O4)(CH3-COO)(H2O) 2, and two new lanthanide-alkali-oxalates coordination polymers KY(C2O4)(2)(H2O)(4) 3, KTb(C2O4)(2)(H2O)(4) 4, have been synthesized under hydrothermal conditions and their structures were determined by single-crystal X-ray diffraction. Structural analysis shows that the two-dimensional (2D) layer structure of complex 1 is built up by the linkages of lanthanide atoms and the oxygen atoms of the bischelating oxalate ligands. In complex 2, for introducing of acetate groups, a 3D network with parallelogram channels (6.3 x 9.4 angstrom) of complex 2 was obtained. The 3D structures of complexes 3 and 4 contain a channel. filled with lattice water molecules, and the potassium atoms are located in the framework. (C) 2008 Elsevier B. V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000263322200005 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66421]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xing, Yongheng |
| 作者单位 | 1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Xingjing,Xing, Yongheng,Wang, Chunguang,et al. Lanthanide-alkali metals-oxalates coordination polymers: Synthesis and structures of [Nd(C2O4)(1.5)(H2O)(3)] center dot 2H(2)O, Nd(C2O4)(CH3COO)(H2O), KLn(C2O4)(2)(H2O)(4) (Ln = Y, Tb)[J]. INORGANICA CHIMICA ACTA,2009,362(4):1058-1064. |
| APA | Zhang, Xingjing.,Xing, Yongheng.,Wang, Chunguang.,Han, Jing.,Li, Jing.,...&Niu, Shuyun.(2009).Lanthanide-alkali metals-oxalates coordination polymers: Synthesis and structures of [Nd(C2O4)(1.5)(H2O)(3)] center dot 2H(2)O, Nd(C2O4)(CH3COO)(H2O), KLn(C2O4)(2)(H2O)(4) (Ln = Y, Tb).INORGANICA CHIMICA ACTA,362(4),1058-1064. |
| MLA | Zhang, Xingjing,et al."Lanthanide-alkali metals-oxalates coordination polymers: Synthesis and structures of [Nd(C2O4)(1.5)(H2O)(3)] center dot 2H(2)O, Nd(C2O4)(CH3COO)(H2O), KLn(C2O4)(2)(H2O)(4) (Ln = Y, Tb)".INORGANICA CHIMICA ACTA 362.4(2009):1058-1064. |
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来源：化学研究所
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