Facile Synthesis of delta-Amino-beta-ketoesters and Piperidinediones via a Vinylogous Mannich-Type Reaction of Brassard-Type Diene with Aldimines without Catalyst
文献类型：期刊论文
| 作者 | Gu, Chun-Ling; Liu, Li; Wang, Dong; Chen, Yong-Jun |
| 刊名 | SYNTHETIC COMMUNICATIONS
 |
| 出版日期 | 2009 |
| 卷号 | 39期号:16页码:2989-3002 |
| 关键词 | Catalyst-free One-pot Process Piperidinedione Vinylogous Mannich |
| ISSN号 | 0039-7911 |
| DOI | 10.1080/00397910902730846 |
| 英文摘要 | The vinylogous Mannich reaction of N-tosyl-aldimines with Brassard diene proceeds at room temperature under catalyst-free conditions smoothly to give gamma-amino-beta-ketoesters (4b-l) in good to excellent yields, which are easily converted to piperidinediones at higher temperature. The two-step reactions could be combined in a one-pot process with toluene as a solvent and without the use of any catalyst for direct synthesis of piperidinediones (5). |
| 语种 | 英语 |
| WOS记录号 | WOS:000267979200020 |
| 出版者 | TAYLOR & FRANCIS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66471]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Li |
| 作者单位 | Chinese Acad Sci, Inst Chem, BNLMS, Biol Chem Lab, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gu, Chun-Ling,Liu, Li,Wang, Dong,et al. Facile Synthesis of delta-Amino-beta-ketoesters and Piperidinediones via a Vinylogous Mannich-Type Reaction of Brassard-Type Diene with Aldimines without Catalyst[J]. SYNTHETIC COMMUNICATIONS,2009,39(16):2989-3002. |
| APA | Gu, Chun-Ling,Liu, Li,Wang, Dong,&Chen, Yong-Jun.(2009).Facile Synthesis of delta-Amino-beta-ketoesters and Piperidinediones via a Vinylogous Mannich-Type Reaction of Brassard-Type Diene with Aldimines without Catalyst.SYNTHETIC COMMUNICATIONS,39(16),2989-3002. |
| MLA | Gu, Chun-Ling,et al."Facile Synthesis of delta-Amino-beta-ketoesters and Piperidinediones via a Vinylogous Mannich-Type Reaction of Brassard-Type Diene with Aldimines without Catalyst".SYNTHETIC COMMUNICATIONS 39.16(2009):2989-3002. |
入库方式： OAI收割
来源：化学研究所
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