Metal-organic frameworks as an acid catalyst for the synthesis of ethyl methyl carbonate via transesterification
文献类型：期刊论文
| 作者 | Zhou, Yinxi; Song, Jinliang; Liang, Shuguang; Hu, Suqin; Liu, Huizhen; Jiang, Tao; Han, Buxing |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 2009-08-04 |
| 卷号 | 308期号:1-2页码:68-72 |
| 关键词 | Metal-organic Frameworks Coordination Polymer Transesterification Ethyl mEthyl Carbonate Dimethyl Carbonate Diethyl Carbonate |
| ISSN号 | 1381-1169 |
| DOI | 10.1016/j.molcata.2009.03.027 |
| 英文摘要 | An efficient synthesis of ethyl methyl carbonate using metal-organic frameworks (MOFs) as Lewis acid catalyst has been realized by the transesterification of dimethyl carbonate and diethyl carbonate. The effects of reaction time, temperature, amount of catalyst and the ratios of substrates on the yield of the objective product were examined. It was demonstrated that MOFs can catalyze the reaction smoothly, and that good yield of ethyl methyl carbonate and high selectivity was achieved under optimized conditions. The catalyst leaching test has shown that the reaction takes place heterogeneously. Moreover, the catalyst can be easily recovered simply by centrifugation and reused over three times without obvious loss of its catalytic activity. (C) 2009 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000268359900009 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66491]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang, Tao |
| 作者单位 | Chinese Acad Sci, BNLMS, Ctr Mol Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Yinxi,Song, Jinliang,Liang, Shuguang,et al. Metal-organic frameworks as an acid catalyst for the synthesis of ethyl methyl carbonate via transesterification[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2009,308(1-2):68-72. |
| APA | Zhou, Yinxi.,Song, Jinliang.,Liang, Shuguang.,Hu, Suqin.,Liu, Huizhen.,...&Han, Buxing.(2009).Metal-organic frameworks as an acid catalyst for the synthesis of ethyl methyl carbonate via transesterification.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,308(1-2),68-72. |
| MLA | Zhou, Yinxi,et al."Metal-organic frameworks as an acid catalyst for the synthesis of ethyl methyl carbonate via transesterification".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 308.1-2(2009):68-72. |
入库方式： OAI收割
来源：化学研究所
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