中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Constructions of a set of hydrogen-bonded supramolecules from reactions of transition metals with 3,5-dimethylpyrazole and different dicarboxylate ligands

文献类型:期刊论文

作者Li, Jing1; Xing, Yong Heng1; Zhao, Hai Yan1; Li, Zhang Peng1; Wang, Chun Guang1; Zeng, Xiao Qing2; Ge, Mao Fa2; Niu, Shun Yun1
刊名INORGANICA CHIMICA ACTA
出版日期2009-06-01
卷号362期号:8页码:2788-2795
关键词Transition Metal Complexes Carboxylate Ligands Crystal Structures Supramolecules 3 5-dimethylpyrazole
ISSN号0020-1693
DOI10.1016/j.ica.2008.12.022
英文摘要Three new supramolecular coordination complexes [Zn(Hdmpz)(2)(O2C(CH2)(2)CO2)](n) (1), Ni-3(Hdmpz)(4)-(HOOC(CH2)(2)CO2)(2)(O2C(CH2)(2)CO2)(2)(CH3OH)(2) (2) and Co-3(Hdmpz)(2)(HOOC(CH2)(3)CO2)(2)(O2C(CH2)(3)CO2)(2)-(CH3OH)(4) (3) (Hdmpz = 3,5-dimethylpyrazol) have been synthesized and characterized by elemental analyses, IR spectra and single crystal X-ray diffraction analysis. Complex 1 is a polymer with the ZnO4N2 core that is interconnected by bridging succinate moieties into a 1D chain structure. Complexes 2 and 3 are discrete structures, both of them have two types of bridging-coordinated modes of carboxylate ligands (mu(3)-eta(2)-eta(2), mu(2)-eta(1)-eta(1)). And there are rich intra- or intermolecular hydrogen bonds in the crystals of 1-3, thereby forming a set of supramolecular frameworks. In addition, the thermal behaviors of 1-3 were also investigated. (C) 2008 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000265509200039
出版者ELSEVIER SCIENCE SA
源URL[http://ir.iccas.ac.cn/handle/121111/66511]  
专题中国科学院化学研究所
通讯作者Xing, Yong Heng
作者单位1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Li, Jing,Xing, Yong Heng,Zhao, Hai Yan,et al. Constructions of a set of hydrogen-bonded supramolecules from reactions of transition metals with 3,5-dimethylpyrazole and different dicarboxylate ligands[J]. INORGANICA CHIMICA ACTA,2009,362(8):2788-2795.
APA Li, Jing.,Xing, Yong Heng.,Zhao, Hai Yan.,Li, Zhang Peng.,Wang, Chun Guang.,...&Niu, Shun Yun.(2009).Constructions of a set of hydrogen-bonded supramolecules from reactions of transition metals with 3,5-dimethylpyrazole and different dicarboxylate ligands.INORGANICA CHIMICA ACTA,362(8),2788-2795.
MLA Li, Jing,et al."Constructions of a set of hydrogen-bonded supramolecules from reactions of transition metals with 3,5-dimethylpyrazole and different dicarboxylate ligands".INORGANICA CHIMICA ACTA 362.8(2009):2788-2795.

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来源:化学研究所

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