Synthesis of a soluble conjugated copolymer based on dialkyl-substituted dithienothiophene and its application in photovoltaic cells
文献类型：期刊论文
| 作者 | Zhang, Shiming1,2,3; He, Chao4; Liu, Yao1,2,3; Zhan, Xiaowei1,2; Chen, Junwu4 |
| 刊名 | POLYMER
 |
| 出版日期 | 2009-07-17 |
| 卷号 | 50期号:15页码:3595-3599 |
| 关键词 | Conjugated Polymer Dithienothiophene Synthesis |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2009.05.031 |
| 英文摘要 | A soluble conjugated alternating 3,5-didecanyldithieno[3,2-b:2',3'-d]thiophene-thiophene copolymer was synthesized by palladium(0)-catalyzed Stille coupling reaction. The thermal, absorption, emission, electrochemical, and photovoltaic properties of the polymer were examined. A weight-average molecular weight around 6.2 x 10(4) and a polyclispersity, index of 1.8 was estimated for the polymer using gel permeation chromatography. The polymer exhibits good thermal stability with decomposition temperature of 340 degrees C and glass-transition temperature of 136 degrees C. The polymer shows strong absorption peaked at 505 nm in diluted solution and 518 nm in thin film with an optical band gap 2.0 eV. The polymer exhibits intense emission located at 550 nm in solution and 603 nm in film. The HOMO and LUMO energies of the polymer were estimated to be -5.4 and -3.4 eV, respectively, by cyclic voltammetry. Polymer solar cells were fabricated based on the blend of the polymer and methanofullerene [6,6]-phenyl C61-butyric acid methyl ester (PCBM). The power conversion efficiency of 0.7% was achieved under AM 1.5, 100 mW/cm(2) using polymer:PCBM (1:4, w/w) as active layer. (C) 2009 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000268306700024 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66641]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhan, Xiaowei |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, CAS Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 4.S China Univ Technol, Inst Polymer Optoelect Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Shiming,He, Chao,Liu, Yao,et al. Synthesis of a soluble conjugated copolymer based on dialkyl-substituted dithienothiophene and its application in photovoltaic cells[J]. POLYMER,2009,50(15):3595-3599. |
| APA | Zhang, Shiming,He, Chao,Liu, Yao,Zhan, Xiaowei,&Chen, Junwu.(2009).Synthesis of a soluble conjugated copolymer based on dialkyl-substituted dithienothiophene and its application in photovoltaic cells.POLYMER,50(15),3595-3599. |
| MLA | Zhang, Shiming,et al."Synthesis of a soluble conjugated copolymer based on dialkyl-substituted dithienothiophene and its application in photovoltaic cells".POLYMER 50.15(2009):3595-3599. |
入库方式： OAI收割
来源：化学研究所
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