Poly(thienylene-vinylene-thienylene) with Cyano Substituent: Synthesis and Application in Field-Effect Transistor and Polymer Solar Cell
文献类型：期刊论文
| 作者 | Wan, Meixiu; Wu, Weiping; Sang, Guangyi; Zou, Yingping; Liu, Yunqi; Li, Yongfang |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2009-08-15 |
| 卷号 | 47期号:16页码:4028-4036 |
| 关键词 | Air-stable Ofet Conjugated Polymers Hole Mobility Modification Poly(Thienylene-vinylene-thienylene) Polymer Solar Cells Uv-vis Spectroscopy |
| ISSN号 | 0887-624X |
| DOI | 10.1002/pola.23464 |
| 英文摘要 | A novel conjugated polymer, poly(thienylene-vinylene-thienylene) with cyano substituent (CN-PTVT) was synthesized via Stille coupling for the application in air stable field-effect transistor and polymer solar cell. The polymer was characterized by (1)H NMR, elemental analysis, UV-vis absorption and photoluminescence spectroscopy, TGA, cyclic voltammetry and XRD analysis. CN-PTVT exhibits a good thermal stability with 5% weight loss at 306 degrees C. The FET hole mobility of the polymer reached 5.9 x 10(-3) cm(2) V(-1) s(-1) with I(on)/I(off) ratio of 4.9 x 10(4), which is one of the highest performance among the air-stable amorphous polymers. The polymer solar cell based on CN-PTVT as donor and PCBM as acceptor shows a relatively high open-circuit voltage of 0.82 V and a power conversion efficiency of 0.3% under the illumination of AM1.5, 100 mW/cm(2). (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 4028-4036, 2009 |
| 语种 | 英语 |
| WOS记录号 | WOS:000268545900007 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66657]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Yongfang |
| 作者单位 | Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wan, Meixiu,Wu, Weiping,Sang, Guangyi,et al. Poly(thienylene-vinylene-thienylene) with Cyano Substituent: Synthesis and Application in Field-Effect Transistor and Polymer Solar Cell[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2009,47(16):4028-4036. |
| APA | Wan, Meixiu,Wu, Weiping,Sang, Guangyi,Zou, Yingping,Liu, Yunqi,&Li, Yongfang.(2009).Poly(thienylene-vinylene-thienylene) with Cyano Substituent: Synthesis and Application in Field-Effect Transistor and Polymer Solar Cell.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,47(16),4028-4036. |
| MLA | Wan, Meixiu,et al."Poly(thienylene-vinylene-thienylene) with Cyano Substituent: Synthesis and Application in Field-Effect Transistor and Polymer Solar Cell".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 47.16(2009):4028-4036. |
入库方式： OAI收割
来源：化学研究所
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