Adsorption of TTF, TCNQ and TTF-TCNQ on Au(111): An in situ ECSTM study
文献类型：期刊论文
| 作者 | Yan HuiJuan; Li ShanShan; Yan CunJi; Chen Qing; Wan LiJun |
| 刊名 | SCIENCE IN CHINA SERIES B-CHEMISTRY
 |
| 出版日期 | 2009-05-01 |
| 卷号 | 52期号:5页码:559-565 |
| 关键词 | Molecular Nanostructure Adsorption Tcnq And Ttf Electrochemical Stm |
| ISSN号 | 1006-9291 |
| DOI | 10.1007/s11426-009-0083-2 |
| 英文摘要 | The adsorption and adlayer structures of tetrathiofulvalene (TTF), tetracyanoquinodimethane ( TCNQ) and TTF-TCNQ on Au(111) have been systematically investigated by in situ electrochemical scanning tunneling microscopy (ECSTM) and cyclic voltammetry in 0.1 mol.L(-1) HClO(4). All the three molecules were found to form well-ordered adlayers in the double-layer potential region of Au(111). For TTF and TCNQ adlayers, (6x3) and (4x7) structures have been observed, respectively. A structural transition was observed on TCNQ adlayer at potential negative of 0.08 V vs. the reversible hydrogen electrode (RHE), and induced a new phase with (3 root 3x12) structure. On the other hand, the charge transfer complex, TTF-TCNQ, self-organized into ordered domains with a lamellar structure different from those of the pure TTF and TCNQ adlayers on Au(111). Its packing arrangement was comparable to surface structures of either single crystal or thin film of TTF-TCNQ. |
| 语种 | 英语 |
| WOS记录号 | WOS:000266094800004 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66763]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wan LiJun |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yan HuiJuan,Li ShanShan,Yan CunJi,et al. Adsorption of TTF, TCNQ and TTF-TCNQ on Au(111): An in situ ECSTM study[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2009,52(5):559-565. |
| APA | Yan HuiJuan,Li ShanShan,Yan CunJi,Chen Qing,&Wan LiJun.(2009).Adsorption of TTF, TCNQ and TTF-TCNQ on Au(111): An in situ ECSTM study.SCIENCE IN CHINA SERIES B-CHEMISTRY,52(5),559-565. |
| MLA | Yan HuiJuan,et al."Adsorption of TTF, TCNQ and TTF-TCNQ on Au(111): An in situ ECSTM study".SCIENCE IN CHINA SERIES B-CHEMISTRY 52.5(2009):559-565. |
入库方式： OAI收割
来源：化学研究所
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