中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Two three-dimensional metal-organic frameworks constructed by multiple building blocks of benzenetricarboxylate and bis(imidazole) ligands

文献类型:期刊论文

作者Liu, Min; Yang, Zhipei; Sun, Wenhao; Li, Xiuping; Li, Juan; Ma, Jinshi; Yang, Guoqiang
刊名INORGANICA CHIMICA ACTA
出版日期2009-06-01
卷号362期号:8页码:2884-2889
关键词Metal-organic Frameworks Hydrothermal Synthesis Multiple Building Blocks Crystal Structures Zinc Coordination Polymers
ISSN号0020-1693
DOI10.1016/j.ica.2009.01.010
英文摘要Two novel metal-organic frameworks [Zn(3)(BTC)(2)(bbi)(3)](n) (1) (H(3)BTC = 1,3,5-benzenetricarboxylate, bbi = 1,1'-(1,4-butanediyl)bis(imidazole)) and{[Zn(3)(BTC)(2)(bix)(3) center dot 2.5H(2)O]}(n) (2) (bix = 1,4-bis(imidazole-1-ylmethyl) benzene) have been hydrothermally prepared and characterized. Analysis of the structure of 1 displays a 3D framework exhibiting a threefold interpenetration net of identical Zn(1.5)(BTC)(bbi)(1.5) single frameworks. In the structure of 2, BTC(3-) and bix build up infinite tubes extending to a 3D non-interpenetrated porous framework. Moderate fluorescent emissions in the solid state at room temperature were observed in both the compounds. (C) 2009 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000265509200054
出版者ELSEVIER SCIENCE SA
源URL[http://ir.iccas.ac.cn/handle/121111/66805]  
专题中国科学院化学研究所
通讯作者Yang, Guoqiang
作者单位Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Photochem, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Liu, Min,Yang, Zhipei,Sun, Wenhao,et al. Two three-dimensional metal-organic frameworks constructed by multiple building blocks of benzenetricarboxylate and bis(imidazole) ligands[J]. INORGANICA CHIMICA ACTA,2009,362(8):2884-2889.
APA Liu, Min.,Yang, Zhipei.,Sun, Wenhao.,Li, Xiuping.,Li, Juan.,...&Yang, Guoqiang.(2009).Two three-dimensional metal-organic frameworks constructed by multiple building blocks of benzenetricarboxylate and bis(imidazole) ligands.INORGANICA CHIMICA ACTA,362(8),2884-2889.
MLA Liu, Min,et al."Two three-dimensional metal-organic frameworks constructed by multiple building blocks of benzenetricarboxylate and bis(imidazole) ligands".INORGANICA CHIMICA ACTA 362.8(2009):2884-2889.

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来源:化学研究所

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