Hydride-Induced Novel Cyclization of Dienedinitriles Leading to Multifunctionalized Cyclopentadienes
文献类型：期刊论文
| 作者 | Zhang, Hui-Jun1,2; Meng, Tianhao3; Demerseman, Bernard1; Bruneau, Christian1; Xi, Zhenfeng2 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2009-10-01 |
| 卷号 | 11期号:19页码:4458-4461 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/ol901840c |
| 英文摘要 | By treatment with LiAIH(4),1,4-dicyano-1,4-bis(trimethylsilyi 1,3-dienes underwent a novel hydride-induced nucleophilic intermolecular 1,4-addition to the 4-unsaturated nitrile moiety, followed by an immediate nucleophilic intramolecular 1,2-addition to the remaining CN group, to afford multiply functionalized cyclopentadienes in high isolated yields. These multifunctional (-CN, -NH(2), -SiMe(3), -H) cyclopentadienes are of a rich and interesting reaction chemistry as preliminarily demonstrated by their reaction with ArNCO involving both the substituent and the ring. |
| 语种 | 英语 |
| WOS记录号 | WOS:000269989100053 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66901]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Bruneau, Christian |
| 作者单位 | 1.Univ Rennes 1, CNRS, UMR 6226, F-35042 Rennes, France 2.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Hui-Jun,Meng, Tianhao,Demerseman, Bernard,et al. Hydride-Induced Novel Cyclization of Dienedinitriles Leading to Multifunctionalized Cyclopentadienes[J]. ORGANIC LETTERS,2009,11(19):4458-4461. |
| APA | Zhang, Hui-Jun,Meng, Tianhao,Demerseman, Bernard,Bruneau, Christian,&Xi, Zhenfeng.(2009).Hydride-Induced Novel Cyclization of Dienedinitriles Leading to Multifunctionalized Cyclopentadienes.ORGANIC LETTERS,11(19),4458-4461. |
| MLA | Zhang, Hui-Jun,et al."Hydride-Induced Novel Cyclization of Dienedinitriles Leading to Multifunctionalized Cyclopentadienes".ORGANIC LETTERS 11.19(2009):4458-4461. |
入库方式： OAI收割
来源：化学研究所
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