Triangle-shaped polycyclic aromatics based on tribenzocoronene: facile synthesis and physical properties
文献类型：期刊论文
| 作者 | Li, Zhongtao1; Zhi, Linjie2; Lucas, Nigel T.3; Wang, Zhaohui1 |
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2009-04-25 |
| 卷号 | 65期号:17页码:3417-3424 |
| 关键词 | Polycyclic Aromatics Packing Arrangement Synthesis Physical Properties |
| ISSN号 | 0040-4020 |
| DOI | 10.1016/j.tet.2009.02.042 |
| 英文摘要 | A series of triangle-shaped polycyclic aromatics have been developed according to a facile synthetic protocol with high yields. As revealed by X-ray single crystal data, their molecular conformation and packing arrangement are significantly influenced by the electronic properties and steric bulk of peripheral subunits. The 'saddle'-shaped hexahalotribenzocoronenes (CITBC and FTBC) possess C(2) symmetric structures and can self-assemble into well-defined columnar Structures, dramatically different from hexabutyoxytribenzocoronene (TBC), which adopts a C(3) symmetric 'double-concave' structure and less efficient packing arrangement. In the compound trithiophenocoronene (TTC), the five-membered corner rings produce a more open bay-region periphery alleviating intramolecular steric congestion. As a result, the molecule adopts an almost planar conformation. (C) 2009 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000265175100010 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66913]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Zhaohui |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing 100080, Peoples R China 2.Natl Ctr Nanosci & Technol China, Beijing 100080, Peoples R China 3.Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia |
| 推荐引用方式 GB/T 7714 | Li, Zhongtao,Zhi, Linjie,Lucas, Nigel T.,et al. Triangle-shaped polycyclic aromatics based on tribenzocoronene: facile synthesis and physical properties[J]. TETRAHEDRON,2009,65(17):3417-3424. |
| APA | Li, Zhongtao,Zhi, Linjie,Lucas, Nigel T.,&Wang, Zhaohui.(2009).Triangle-shaped polycyclic aromatics based on tribenzocoronene: facile synthesis and physical properties.TETRAHEDRON,65(17),3417-3424. |
| MLA | Li, Zhongtao,et al."Triangle-shaped polycyclic aromatics based on tribenzocoronene: facile synthesis and physical properties".TETRAHEDRON 65.17(2009):3417-3424. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。