3D Hollow Microspheres Assembled from 1D Polyaniline Nanowires through a Cooperation Reaction
文献类型:期刊论文
作者 | Zhu, Ying1; Ren, Guanqiao2; Wan, Meixiang2; Jiang, Lei1,2 |
刊名 | MACROMOLECULAR CHEMISTRY AND PHYSICS
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出版日期 | 2009-12-04 |
卷号 | 210期号:23页码:2046-2051 |
关键词 | Cooperation Effect Hollow Spheres Nanofibers Polyaniline Self-assembly |
ISSN号 | 1022-1352 |
DOI | 10.1002/macp.200900317 |
英文摘要 | Novel 3D hollow spheres (diameter approximate to 525 nm, thickness, approximate to 70 nm) self-assembled from 1D PANI nanofibers (diameter approximate to 17 nm) with conductivity of 1.11 x 10(-1) S . cm(-1) are synthesized template-free by using FeCl(3) and salicylic acid as the oxidant and dopant, respectively. In this method, the reaction of aniline with FeCl(3) and SA to form conductive PANI and the reaction of SA with FeCl(3) to produce a color complex, assigned as Fe(OR)(2+), wherein OR represents the ionized phenol, coexist. The coexistence of two reactions results in a cooperative effect of the micelle, where aniline/SA acts as as a soft template of the nanofibers and the color complex as a soft-template of the spheres, to allow the self-assembly of complex micro/nanostructures via hydrogen bonding as the driving force. |
语种 | 英语 |
WOS记录号 | WOS:000272756400006 |
出版者 | WILEY-V C H VERLAG GMBH |
源URL | [http://ir.iccas.ac.cn/handle/121111/66925] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zhu, Ying |
作者单位 | 1.Beijing Univ Aeronaut & Astronaut, Sch Chem & Environm, Beijing 100191, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Zhu, Ying,Ren, Guanqiao,Wan, Meixiang,et al. 3D Hollow Microspheres Assembled from 1D Polyaniline Nanowires through a Cooperation Reaction[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2009,210(23):2046-2051. |
APA | Zhu, Ying,Ren, Guanqiao,Wan, Meixiang,&Jiang, Lei.(2009).3D Hollow Microspheres Assembled from 1D Polyaniline Nanowires through a Cooperation Reaction.MACROMOLECULAR CHEMISTRY AND PHYSICS,210(23),2046-2051. |
MLA | Zhu, Ying,et al."3D Hollow Microspheres Assembled from 1D Polyaniline Nanowires through a Cooperation Reaction".MACROMOLECULAR CHEMISTRY AND PHYSICS 210.23(2009):2046-2051. |
入库方式: OAI收割
来源:化学研究所
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