中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
3D Hollow Microspheres Assembled from 1D Polyaniline Nanowires through a Cooperation Reaction

文献类型:期刊论文

作者Zhu, Ying1; Ren, Guanqiao2; Wan, Meixiang2; Jiang, Lei1,2
刊名MACROMOLECULAR CHEMISTRY AND PHYSICS
出版日期2009-12-04
卷号210期号:23页码:2046-2051
关键词Cooperation Effect Hollow Spheres Nanofibers Polyaniline Self-assembly
ISSN号1022-1352
DOI10.1002/macp.200900317
英文摘要Novel 3D hollow spheres (diameter approximate to 525 nm, thickness, approximate to 70 nm) self-assembled from 1D PANI nanofibers (diameter approximate to 17 nm) with conductivity of 1.11 x 10(-1) S . cm(-1) are synthesized template-free by using FeCl(3) and salicylic acid as the oxidant and dopant, respectively. In this method, the reaction of aniline with FeCl(3) and SA to form conductive PANI and the reaction of SA with FeCl(3) to produce a color complex, assigned as Fe(OR)(2+), wherein OR represents the ionized phenol, coexist. The coexistence of two reactions results in a cooperative effect of the micelle, where aniline/SA acts as as a soft template of the nanofibers and the color complex as a soft-template of the spheres, to allow the self-assembly of complex micro/nanostructures via hydrogen bonding as the driving force.
语种英语
WOS记录号WOS:000272756400006
出版者WILEY-V C H VERLAG GMBH
源URL[http://ir.iccas.ac.cn/handle/121111/66925]  
专题中国科学院化学研究所
通讯作者Zhu, Ying
作者单位1.Beijing Univ Aeronaut & Astronaut, Sch Chem & Environm, Beijing 100191, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Zhu, Ying,Ren, Guanqiao,Wan, Meixiang,et al. 3D Hollow Microspheres Assembled from 1D Polyaniline Nanowires through a Cooperation Reaction[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2009,210(23):2046-2051.
APA Zhu, Ying,Ren, Guanqiao,Wan, Meixiang,&Jiang, Lei.(2009).3D Hollow Microspheres Assembled from 1D Polyaniline Nanowires through a Cooperation Reaction.MACROMOLECULAR CHEMISTRY AND PHYSICS,210(23),2046-2051.
MLA Zhu, Ying,et al."3D Hollow Microspheres Assembled from 1D Polyaniline Nanowires through a Cooperation Reaction".MACROMOLECULAR CHEMISTRY AND PHYSICS 210.23(2009):2046-2051.

入库方式: OAI收割

来源:化学研究所

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