Haloperoxidase-like Compounds: Synthesis, Structure and Properties of Two New Oxidovanadium-Poly(pyrazolyl)borate-Carboxylate Complexes
文献类型：期刊论文
| 作者 | Li, Zhang-Peng1; Xing, Yong-Heng1; Wang, Chun-Guang1; Li, Jing1; Cao, Yun-Zhu1; Zeng, Xiao-Qing2; Ge, Mao-Fa2; Niu, Shu-Yun1 |
| 刊名 | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
 |
| 出版日期 | 2009 |
| 卷号 | 635期号:15页码:2601-2607 |
| 关键词 | Vanadium Haloperoxidases Poly(Pyrazolyl)Borates Carboxylates X-ray Diffraction |
| ISSN号 | 0044-2313 |
| DOI | 10.1002/zaac.200900198 |
| 英文摘要 | Two new oxidovanadium (IV) complexes: TpVO(L-1) (1) and Tp*VO(pzH*)(L-2) (2) [Tp = hydrotris(pyrazolyl)borate, HL1 = 5-methyl-1H-pyrazole-3-carboxylic acid, Tp* = hydrotris(3,5-dimethyl-pyrazolyl)borate,pzH*=3,5-dimethylpyrazole, HL2=5-phenyl-1H-pyra zole-3-carboxylic acid] have been synthesized and characterized by elemental analysis and IR spectroscopy. The single-crystal structures of the complexes shows that the vanadium ion is in a distorted octahedral environment with a N4O2 donor set in each complex. Additionally, hydrogen bonding interaction exits in both complexes. Interestingly, the molecules of I are held together to form a ID hydrogen bonded polymer along the b axis, whereas complex 2 is a hydrogen bonded dimer. In addition, the catalytic activities of complexes 1 and 2 in bromination reactions in phosphate buffer with phenol red as a trap were evaluated primary by UV/Vis spectroscopy. Furthermore, ab initio calculations of complexes 1 and 2 were performed. |
| 语种 | 英语 |
| WOS记录号 | WOS:000273393800038 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/66951]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xing, Yong-Heng |
| 作者单位 | 1.Liaoning Normal Univ, Coll Chem & Chem Engn, Bioinorgan Lab, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Zhang-Peng,Xing, Yong-Heng,Wang, Chun-Guang,et al. Haloperoxidase-like Compounds: Synthesis, Structure and Properties of Two New Oxidovanadium-Poly(pyrazolyl)borate-Carboxylate Complexes[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2009,635(15):2601-2607. |
| APA | Li, Zhang-Peng.,Xing, Yong-Heng.,Wang, Chun-Guang.,Li, Jing.,Cao, Yun-Zhu.,...&Niu, Shu-Yun.(2009).Haloperoxidase-like Compounds: Synthesis, Structure and Properties of Two New Oxidovanadium-Poly(pyrazolyl)borate-Carboxylate Complexes.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,635(15),2601-2607. |
| MLA | Li, Zhang-Peng,et al."Haloperoxidase-like Compounds: Synthesis, Structure and Properties of Two New Oxidovanadium-Poly(pyrazolyl)borate-Carboxylate Complexes".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 635.15(2009):2601-2607. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。