Electrochemistry of Sc3N@C-78 embedded in didodecyldimethylammonium bromide films in aqueous solution
文献类型：期刊论文
| 作者 | Zhao, Mingyan1; Zhang, Lin1; Chen, Ning2; Wang, Chunru2; Fan, Louzhen1; Yang, Shihe3 |
| 刊名 | MICROCHIMICA ACTA
 |
| 出版日期 | 2009-04-01 |
| 卷号 | 165期号:1-2页码:45-52 |
| 关键词 | Sc3n@c-78 Ddab Films Electrochemistry |
| ISSN号 | 0026-3672 |
| DOI | 10.1007/s00604-008-0095-1 |
| 英文摘要 | The electrochemical behavior of trimetallic nitride clusterfullerene (Sc3N@C-78) embedded in films of the cationic surfactant didodecyldimethylammonium bromide (DDAB) on glassy carbon (GC) electrodes in aqueous solution was investigated. Four pairs of reversible redox peaks were observed in the potential range between +0.6 and -0.9 V vs. SCE. Different to the electrochemistry of pristine Sc3N@C-78 in organic solution, the first reduction is a one-electron rather than simultaneous two-electron process because of the strong binding between DDA(+) and the monoanion of Sc3N@C-78. The generated radial monoanion, dianion and trianion of Sc3N@C-78 are stable during continuous potential cycling, while some chemical reactions take place when the third anion is further reduced in the films. The cyclic voltammograms of Sc3N@C-78/DDAB films checked at different temperatures pointed to strong temperature dependence. The electrochemical processes were also measured in different electrolytes, which showed pronounced anionic dependence and no cathodic dependence on either the cation or anions present. A possible electron-transfer mechanism of a Sc3N@C-78/DDAB film was presented. |
| 语种 | 英语 |
| WOS记录号 | WOS:000264487000006 |
| 出版者 | SPRINGER WIEN |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/67025]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Fan, Louzhen |
| 作者单位 | 1.Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 3.Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Mingyan,Zhang, Lin,Chen, Ning,et al. Electrochemistry of Sc3N@C-78 embedded in didodecyldimethylammonium bromide films in aqueous solution[J]. MICROCHIMICA ACTA,2009,165(1-2):45-52. |
| APA | Zhao, Mingyan,Zhang, Lin,Chen, Ning,Wang, Chunru,Fan, Louzhen,&Yang, Shihe.(2009).Electrochemistry of Sc3N@C-78 embedded in didodecyldimethylammonium bromide films in aqueous solution.MICROCHIMICA ACTA,165(1-2),45-52. |
| MLA | Zhao, Mingyan,et al."Electrochemistry of Sc3N@C-78 embedded in didodecyldimethylammonium bromide films in aqueous solution".MICROCHIMICA ACTA 165.1-2(2009):45-52. |
入库方式： OAI收割
来源：化学研究所
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