New cyano-substituted copolymers containing biphenylenevinylene and bithienylenevinylene units: synthesis, optical, and electrochemical properties
文献类型：期刊论文
| 作者 | Zou, Yingping1; Liu, Bo1; Li, Yongfang2; He, Yuehui3; Zhou, Kechao3; Pan, Chunyue1 |
| 刊名 | JOURNAL OF MATERIALS SCIENCE
 |
| 出版日期 | 2009-08-01 |
| 卷号 | 44期号:15页码:4174-4180 |
| ISSN号 | 0022-2461 |
| DOI | 10.1007/s10853-009-3622-5 |
| 英文摘要 | Two new cyano-substituted copolymers containing biphenylenevinylene and bithienylenevinylene moieties (DCN-PPV and DCN-PTV) were synthesized by a stille condensation reaction with Pd(PPh(3))(4) as catalyst. Their structures were confirmed by (1)H NMR, IR spectroscopy, and elemental analysis. The thermal, optical, and electrochemical properties of the polymers were investigated. The results show that the polymers possess high thermal decomposition temperature and reversible n-doping/dedoping processes. In addition, DCN-PTV has higher electron affinity with a low LUMO energy level of -3.84 eV and a relatively broader absorption band covering 300-780 nm, indicating that DCN-PTV could be a potential n-type conjugated polymer in optoelectronic devices. |
| 语种 | 英语 |
| WOS记录号 | WOS:000266911600036 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/67047]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zou, Yingping |
| 作者单位 | 1.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China 3.Cent S Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zou, Yingping,Liu, Bo,Li, Yongfang,et al. New cyano-substituted copolymers containing biphenylenevinylene and bithienylenevinylene units: synthesis, optical, and electrochemical properties[J]. JOURNAL OF MATERIALS SCIENCE,2009,44(15):4174-4180. |
| APA | Zou, Yingping,Liu, Bo,Li, Yongfang,He, Yuehui,Zhou, Kechao,&Pan, Chunyue.(2009).New cyano-substituted copolymers containing biphenylenevinylene and bithienylenevinylene units: synthesis, optical, and electrochemical properties.JOURNAL OF MATERIALS SCIENCE,44(15),4174-4180. |
| MLA | Zou, Yingping,et al."New cyano-substituted copolymers containing biphenylenevinylene and bithienylenevinylene units: synthesis, optical, and electrochemical properties".JOURNAL OF MATERIALS SCIENCE 44.15(2009):4174-4180. |
入库方式： OAI收割
来源：化学研究所
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