Unexpected Regioselectivity in the Synthesis of Pyranonaphthoquinone via the Diels-Alder Reaction
文献类型：期刊论文
| 作者 | Cui, Yi1,2,3; Jiang, Hao4; Li, Zhengtao1,2,3; Wu, Na1,2,3; Yang, Zhen1,2,3; Quan, Junmin1,2,3 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2009-10-15 |
| 卷号 | 11期号:20页码:4628-4631 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/ol901902v |
| 英文摘要 | The unusual regioselectivity in the Diels-Alder reactions of pyranoquinone 1 with (4,4-dimethoxybuta-1,3-dien-2-yloxy)trimethylsilane 2 are explored by both computations and experiments. The regioselectivity is controlled by the electrostatic interaction of the lactone ring-oxygen and the vicinal quinone oxygen on the transition structure, which can be tuned by the terminal methyl group of the butadienes. |
| 语种 | 英语 |
| WOS记录号 | WOS:000270461300037 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/67057]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Zhen |
| 作者单位 | 1.Beijing Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Beijing 100871, Peoples R China 2.Peking Univ, Shenzhen Grad Sch, Lab Chem Genom, Shenzhen 518055, Peoples R China 3.Beijing Univ, Coll Chem, BNLMS, Beijing 100871, Peoples R China 4.Jinan Univ, Coll Pharm, Inst Tradit Chinese Med & Nat Prod, Guangzhou 510632, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cui, Yi,Jiang, Hao,Li, Zhengtao,et al. Unexpected Regioselectivity in the Synthesis of Pyranonaphthoquinone via the Diels-Alder Reaction[J]. ORGANIC LETTERS,2009,11(20):4628-4631. |
| APA | Cui, Yi,Jiang, Hao,Li, Zhengtao,Wu, Na,Yang, Zhen,&Quan, Junmin.(2009).Unexpected Regioselectivity in the Synthesis of Pyranonaphthoquinone via the Diels-Alder Reaction.ORGANIC LETTERS,11(20),4628-4631. |
| MLA | Cui, Yi,et al."Unexpected Regioselectivity in the Synthesis of Pyranonaphthoquinone via the Diels-Alder Reaction".ORGANIC LETTERS 11.20(2009):4628-4631. |
入库方式： OAI收割
来源：化学研究所
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