Novel Electromagnetic Functionalized gamma-Fe2O3/Polypyrrole Composite Nanostructures with High Conductivity
文献类型：期刊论文
| 作者 | Xiao, Hong-Mei1,2; Zhang, Wei-Dong2; Wan, Mei-Xiang1; Fu, Shao-Yun2 |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2009-09-01 |
| 卷号 | 47期号:17页码:4446-4453 |
| ISSN号 | 0887-624X |
| 关键词 | Chemical Synthesis Composite Nanostructures Conducting Polymers Electromagnetic Function Polypyrrole |
| DOI | 10.1002/pola.23500 |
| 英文摘要 | In general, the conductivity of polypyrrole (PPy) is reduced by addition of magnetic nanoparticles as the additives owing to insulating effect of magnetic nanoparticles. In this article, novel electromagnetic functionalized PPy composite nanostructures were prepared by a template-free method associated with gamma-Fe2O3 nano-needles as the hard templates in the presence of p-toluene-sulfonic acid (p-TSA) and FeCl3 center dot 6H(2)O as the dopant and oxidant, respectively. It was found that the molar ratio of gamma-Fe2O3 to pyrrole monomer represented by [gamma-Fe2O3]/[Py] ratio strongly affected the morphology and the conductivity of the gamma-Fe2O3/PPy composite nanostructures. A growth mechanism for the composite nanostructures was proposed based on the variance of the morphology with the [gamma-Fe2O3]/[Py] ratio. Compared with previously reported gamma-Fe2O3/PPy composites, the as-prepared novel composite nanostructures showed much higher conductivity (up to similar to 50 times higher). Moreover, the synthesized gamma-Fe2O3/PPy composite nanostructures displayed ferromagnetic behavior with a high coercive force. Explanations for these interesting observations were made in terms of the magnetic interaction between ferromagnetic gamma-Fe2O3 nano-needles and spin-polaron of PPy nanotubes. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 4446-4453, 2009 |
| 语种 | 英语 |
| 出版者 | WILEY-BLACKWELL |
| WOS记录号 | WOS:000269090300021 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/67091]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wan, Mei-Xiang |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiao, Hong-Mei,Zhang, Wei-Dong,Wan, Mei-Xiang,et al. Novel Electromagnetic Functionalized gamma-Fe2O3/Polypyrrole Composite Nanostructures with High Conductivity[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2009,47(17):4446-4453. |
| APA | Xiao, Hong-Mei,Zhang, Wei-Dong,Wan, Mei-Xiang,&Fu, Shao-Yun.(2009).Novel Electromagnetic Functionalized gamma-Fe2O3/Polypyrrole Composite Nanostructures with High Conductivity.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,47(17),4446-4453. |
| MLA | Xiao, Hong-Mei,et al."Novel Electromagnetic Functionalized gamma-Fe2O3/Polypyrrole Composite Nanostructures with High Conductivity".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 47.17(2009):4446-4453. |
入库方式： OAI收割
来源：化学研究所
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