中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Electrochemical sensing of ATP with synthetic cyclophane as recognition element

文献类型:期刊论文

作者Ma YuRong2; Zhao Hong2; Yu Ping1; Su Lei1; Zhang DeQing1; Mao LanQun1
刊名SCIENCE IN CHINA SERIES B-CHEMISTRY
出版日期2009-06-01
卷号52期号:6页码:741-745
关键词Electrochemistry Sensor Atp Clyclophane
ISSN号1006-9291
DOI10.1007/s11426-009-0074-3
英文摘要A new electrochemical sensor for ATP with synthetic cyclophane stably attached onto single-walled carbon nanotubes (SWNTs) as the recognition elements is described. UV-vis and cyclic voltammetric results demonstrate that ATP may interact with the synthetic cyclophane recognition elements to form a stable adduct mainly through electrostatic, pi-pi stacking and donor-acceptor interactions. Such interactions eventually lead to a decrease in the peak currents of the cyclophane recognition elements attached onto the SWNT electronic transducer, which could be used for electrochemical sensing of ATP. Under the conditions employed here, the ratio of the decrease in the anodic peak current is linear with ATP concentration within a concentration range from 10 to 120 mu M with a linear coefficiency of 0.993. This study may offer a new and simple electrochemical approach for effective sensing of ATP.
语种英语
WOS记录号WOS:000266168000006
出版者SCIENCE PRESS
源URL[http://ir.iccas.ac.cn/handle/121111/67141]  
专题中国科学院化学研究所
通讯作者Mao LanQun
作者单位1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Ma YuRong,Zhao Hong,Yu Ping,et al. Electrochemical sensing of ATP with synthetic cyclophane as recognition element[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2009,52(6):741-745.
APA Ma YuRong,Zhao Hong,Yu Ping,Su Lei,Zhang DeQing,&Mao LanQun.(2009).Electrochemical sensing of ATP with synthetic cyclophane as recognition element.SCIENCE IN CHINA SERIES B-CHEMISTRY,52(6),741-745.
MLA Ma YuRong,et al."Electrochemical sensing of ATP with synthetic cyclophane as recognition element".SCIENCE IN CHINA SERIES B-CHEMISTRY 52.6(2009):741-745.

入库方式: OAI收割

来源:化学研究所

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