Synthesis of a graft polymer PVAc-g-[P(AN-r-BVE)-b-PCHO] in "one-step" by radical/cationic transformation polymerization and coupling reaction
文献类型：期刊论文
| 作者 | Lai, Renfu1; Guo, Haiqing1; Kamachi, Mikuharu2 |
| 刊名 | POLYMER
 |
| 出版日期 | 2009-07-17 |
| 卷号 | 50期号:15页码:3582-3586 |
| 关键词 | One-step Graft Polymer Transformation Polymerization |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2009.06.002 |
| 英文摘要 | This article reports a new "one-step" synthesis of graft polymers based on the radical/cationic transformation polymerization. Using the synthetic method proposed, a graft polymer (PVAc-g-[P(AN-r-BVE)-b-PCHO]) consisting of a partly hydrolyzed poly(vinyl acetate) (PVAc-OH) backbone and block polymer grafts of acrylonitrile/n-butyl vinyl ether random copolymer (P(AN-r-BVE)) and poly(cyclohexene oxide) (PCHO) was synthesized in situ by radical/cationic transformation polymerization of a mixture of AN/ BVE/CHO in the presence of PVAc-OH. The graft polymer, PVAc-g-[P(AN-r-BVE)-b-PCHO], was fully characterized by (1)H NIMR, IR. gel permeation chromatography and differential scanning calorimetry. The graft polymer, PVAc-g-[P(AN-r-BVE)-b-PCHO], was hydrolyzed with NaOH to form a poly(vinyl alcohol)-based amphiphilic graft polymer, PVA-g-[P(AN-r-BVE)-b-PCHO]. The aggregation behavior of the amphiphilic graft polymer was investigated briefly by atomic force microscopy and dynamic light scattering measurements. (C) 2009 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000268306700022 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/67145]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Guo, Haiqing |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Fukui Univ Technol, Dept Appl Phys & Chem, Fukui 9100028, Japan |
| 推荐引用方式 GB/T 7714 | Lai, Renfu,Guo, Haiqing,Kamachi, Mikuharu. Synthesis of a graft polymer PVAc-g-[P(AN-r-BVE)-b-PCHO] in "one-step" by radical/cationic transformation polymerization and coupling reaction[J]. POLYMER,2009,50(15):3582-3586. |
| APA | Lai, Renfu,Guo, Haiqing,&Kamachi, Mikuharu.(2009).Synthesis of a graft polymer PVAc-g-[P(AN-r-BVE)-b-PCHO] in "one-step" by radical/cationic transformation polymerization and coupling reaction.POLYMER,50(15),3582-3586. |
| MLA | Lai, Renfu,et al."Synthesis of a graft polymer PVAc-g-[P(AN-r-BVE)-b-PCHO] in "one-step" by radical/cationic transformation polymerization and coupling reaction".POLYMER 50.15(2009):3582-3586. |
入库方式： OAI收割
来源：化学研究所
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