Facile synthesis of elongated calcite superstructure by triblock copolymers with precisely designed block length
文献类型：期刊论文
| 作者 | Su, Yunlan; Wang, Dexiu; Yang, Hengrui; Wang, Dujin |
| 刊名 | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
 |
| 出版日期 | 2009-06-15 |
| 卷号 | 342期号:1-3页码:122-126 |
| 关键词 | Elongated Calcite Triblock Copolymer Block Length Oriented Attachment |
| ISSN号 | 0927-7757 |
| DOI | 10.1016/j.colsurfa.2009.04.027 |
| 英文摘要 | Calcite crystals elongated along the c-axis and capped by (104) rhombohedral faces were grown in the solutions of two kinds of triblock copolymers poly (ethylene glycol)-block-poly (acrylic acid)-block-poly (n-butyl acrylate) (PEG-b-PAA-b-PnBA) with different PAA block length. The copolymer with 3:1 PEG:PAA block ratio facilitates the formation of spindle-shaped calcite elongated along the c-axis and with curved (100) or (110) prismatic faces. CaCO(3) obtained from the copolymer with 6:1 PEG:PAA block ratio exhibits stack-like calcite elongated along the c-axis and with no newly developed faces. The formation of elongated calcite could be due to the aggregation of nanoparticles via an oriented attachment mechanism. The calcite crystals recovered their rhombohedral {104} faces gradually with decreasing PAA block length from 3:1 to 6:1 PEG:PAA block ratio, which could be attributed to the weakening of the inhibition efficiency of the PAA block on the non-rhombohedral planes. (c) 2009 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000267095500019 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/67215]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Dujin |
| 作者单位 | Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Su, Yunlan,Wang, Dexiu,Yang, Hengrui,et al. Facile synthesis of elongated calcite superstructure by triblock copolymers with precisely designed block length[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2009,342(1-3):122-126. |
| APA | Su, Yunlan,Wang, Dexiu,Yang, Hengrui,&Wang, Dujin.(2009).Facile synthesis of elongated calcite superstructure by triblock copolymers with precisely designed block length.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,342(1-3),122-126. |
| MLA | Su, Yunlan,et al."Facile synthesis of elongated calcite superstructure by triblock copolymers with precisely designed block length".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 342.1-3(2009):122-126. |
入库方式： OAI收割
来源：化学研究所
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