A novel glycidyl methacrylate-based monolith with sub-micron skeletons and well-defined macropores
文献类型：期刊论文
| 作者 | Yao, Chunhe1,2; Qi, Li1; Jia, Hongying1; Xin, Peiyong1,2; Yang, Gengliang3; Chen, Yi1 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY
 |
| 出版日期 | 2009 |
| 卷号 | 19期号:6页码:767-772 |
| ISSN号 | 0959-9428 |
| DOI | 10.1039/b816712e |
| 英文摘要 | A series of glycidyl methacrylate-based polymer monoliths, including spherical walled structures, submicron skeletons, and lamellar morphologies, are reproducibly prepared by high internal phase emulsions in combination with block copolymer chemistry. The morphologies could be manipulated over a wide range by only altering the typical tri-block copolymer (Pluronic F127) concentration. The ability of the Pluronic F127 to direct supramolecular self-assembly is the main reason for the rich phase behavior exhibited such as the micellar phase (i.e., spherical micelles, wormlike micelles), the bicontinuous phase, and the lamellar phase. Equally important, the glycidyl methacrylate-based monoliths differ significantly from conventional polymer monoliths; they have sub-micron skeletons (100-1000 nm), micrometer-sized throughpores, relatively large specific surface area (161 m(2) g(-1)), and excellent permeability (6.1 x 10(13) m(2)). Further, the monoliths display superiority in fast and high-throughput separation of proteins. This, together with easy fabrication makes the novel monoliths a promising alternative to commercially available monolithic supports. |
| 语种 | 英语 |
| WOS记录号 | WOS:000262850400013 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/67365]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Qi, Li |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Lab Analyt Chem Life Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China 3.Hebei Univ, Coll Pharm, Baoding 071002, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yao, Chunhe,Qi, Li,Jia, Hongying,et al. A novel glycidyl methacrylate-based monolith with sub-micron skeletons and well-defined macropores[J]. JOURNAL OF MATERIALS CHEMISTRY,2009,19(6):767-772. |
| APA | Yao, Chunhe,Qi, Li,Jia, Hongying,Xin, Peiyong,Yang, Gengliang,&Chen, Yi.(2009).A novel glycidyl methacrylate-based monolith with sub-micron skeletons and well-defined macropores.JOURNAL OF MATERIALS CHEMISTRY,19(6),767-772. |
| MLA | Yao, Chunhe,et al."A novel glycidyl methacrylate-based monolith with sub-micron skeletons and well-defined macropores".JOURNAL OF MATERIALS CHEMISTRY 19.6(2009):767-772. |
入库方式： OAI收割
来源：化学研究所
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