Highly selective synthesis of triptycene o-quinone derivatives and their optical and electrochemical properties
文献类型:期刊论文
作者 | Zhao, Jian-Min1,2; Lu, Hai-Yan2; Cao, Jing1,2; Jiang, Yi1,2; Chen, Chuan-Feng1 |
刊名 | TETRAHEDRON LETTERS
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出版日期 | 2009-01-14 |
卷号 | 50期号:2页码:219-222 |
关键词 | Triptycene O-quinone Selective Synthesis Intramolecular Ct interaCtion Optical And Electrochemical Properties Dft Calculation |
ISSN号 | 0040-4039 |
DOI | 10.1016/j.tetlet.2008.10.128 |
英文摘要 | A convenient and efficient method for the selective synthesis of a series of triptycene o-quinone derivatives is described. The triptycene o-quinones, especially the ones containing the methoxy group(s) (electron donor) and the o-quinone group(s) (electron acceptor) simultaneously, show interesting intramolecular CT interactions and electrochemical properties. Moreover. DFT calculations display that introducing a strong electron-donor group into triptycene o-quinone results in an increasing of the HOMO energy level, which Subsequently decreases the HOMO-LUMO energy gap. (c) 2008 Elsevier Ltd. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000263218700021 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/67391] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Chen, Chuan-Feng |
作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Ctr Chem Biol, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, Jian-Min,Lu, Hai-Yan,Cao, Jing,et al. Highly selective synthesis of triptycene o-quinone derivatives and their optical and electrochemical properties[J]. TETRAHEDRON LETTERS,2009,50(2):219-222. |
APA | Zhao, Jian-Min,Lu, Hai-Yan,Cao, Jing,Jiang, Yi,&Chen, Chuan-Feng.(2009).Highly selective synthesis of triptycene o-quinone derivatives and their optical and electrochemical properties.TETRAHEDRON LETTERS,50(2),219-222. |
MLA | Zhao, Jian-Min,et al."Highly selective synthesis of triptycene o-quinone derivatives and their optical and electrochemical properties".TETRAHEDRON LETTERS 50.2(2009):219-222. |
入库方式: OAI收割
来源:化学研究所
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