中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Highly selective synthesis of triptycene o-quinone derivatives and their optical and electrochemical properties

文献类型:期刊论文

作者Zhao, Jian-Min1,2; Lu, Hai-Yan2; Cao, Jing1,2; Jiang, Yi1,2; Chen, Chuan-Feng1
刊名TETRAHEDRON LETTERS
出版日期2009-01-14
卷号50期号:2页码:219-222
关键词Triptycene O-quinone Selective Synthesis Intramolecular Ct interaCtion Optical And Electrochemical Properties Dft Calculation
ISSN号0040-4039
DOI10.1016/j.tetlet.2008.10.128
英文摘要A convenient and efficient method for the selective synthesis of a series of triptycene o-quinone derivatives is described. The triptycene o-quinones, especially the ones containing the methoxy group(s) (electron donor) and the o-quinone group(s) (electron acceptor) simultaneously, show interesting intramolecular CT interactions and electrochemical properties. Moreover. DFT calculations display that introducing a strong electron-donor group into triptycene o-quinone results in an increasing of the HOMO energy level, which Subsequently decreases the HOMO-LUMO energy gap. (c) 2008 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000263218700021
出版者PERGAMON-ELSEVIER SCIENCE LTD
源URL[http://ir.iccas.ac.cn/handle/121111/67391]  
专题中国科学院化学研究所
通讯作者Chen, Chuan-Feng
作者单位1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Ctr Chem Biol, Inst Chem, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhao, Jian-Min,Lu, Hai-Yan,Cao, Jing,et al. Highly selective synthesis of triptycene o-quinone derivatives and their optical and electrochemical properties[J]. TETRAHEDRON LETTERS,2009,50(2):219-222.
APA Zhao, Jian-Min,Lu, Hai-Yan,Cao, Jing,Jiang, Yi,&Chen, Chuan-Feng.(2009).Highly selective synthesis of triptycene o-quinone derivatives and their optical and electrochemical properties.TETRAHEDRON LETTERS,50(2),219-222.
MLA Zhao, Jian-Min,et al."Highly selective synthesis of triptycene o-quinone derivatives and their optical and electrochemical properties".TETRAHEDRON LETTERS 50.2(2009):219-222.

入库方式: OAI收割

来源:化学研究所

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