Highly crystalline and thin polyaniline nanofibers oxidized by ferric chloride
文献类型：期刊论文
| 作者 | Zhang, Zhiming1,2; Deng, Junying1,2; Wan, Meixiang1 |
| 刊名 | MATERIALS CHEMISTRY AND PHYSICS
 |
| 出版日期 | 2009-05-15 |
| 卷号 | 115期号:1页码:275-279 |
| 关键词 | Nanostructures Conducting Polymers Nanofibers Ferric Chloride |
| ISSN号 | 0254-0584 |
| DOI | 10.1016/j.matchemphys.2008.12.005 |
| 英文摘要 | Highly crystalline polyaniline (PANI) nanofibers with 16-23 nm in diameter were successfully prepared by using FeCl(3)center dot 6H(2)O as the oxidant in the presence of inorganic acids (e.g. HCl, H(2)SO(4), H(3)PO(4) and H F) without any external template. It is found that the effects of the dopant structure and the molar ratio of FeCl(3) to aniline on the morphology and diameter of the resulting PANI nanofibers are weak when FeCl(3)center dot 6H(2)O was used as the oxidant. It is proposed that low redox potential of FeCl(3) results in thin nanofibers with similar to 20nm in average diameter, indicating that FeCl(3) is an excellent oxidant to prepare really nano-scaled fibers or tubes of PANI or its derivatives via a self-assembly process. (C) 2008 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000264841900050 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/67441]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wan, Meixiang |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 2.Ocean Univ China, Minist Educ, Key Lab Marine Chem Theory & Technol, Coll Chem & Chem Engn, Qingdao 2661002, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Zhiming,Deng, Junying,Wan, Meixiang. Highly crystalline and thin polyaniline nanofibers oxidized by ferric chloride[J]. MATERIALS CHEMISTRY AND PHYSICS,2009,115(1):275-279. |
| APA | Zhang, Zhiming,Deng, Junying,&Wan, Meixiang.(2009).Highly crystalline and thin polyaniline nanofibers oxidized by ferric chloride.MATERIALS CHEMISTRY AND PHYSICS,115(1),275-279. |
| MLA | Zhang, Zhiming,et al."Highly crystalline and thin polyaniline nanofibers oxidized by ferric chloride".MATERIALS CHEMISTRY AND PHYSICS 115.1(2009):275-279. |
入库方式： OAI收割
来源：化学研究所
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