A Self-Assembled Foldamer Capsule: Combining Single and Double Helical Segments in One Aromatic Amide Sequence
文献类型：期刊论文
| 作者 | Bao, Chunyan; Gan, Quan1,2; Kauffmann, Brice; Jiang, Hua1,2; Huc, Ivan |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2009 |
| 卷号 | 15期号:43页码:11530-11536 |
| 关键词 | Chirality Helical Structures Molecular Recognition Supramolecular Chemistry X-ray Diffraction |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.200900877 |
| 英文摘要 | In this manuscript, we present supramolecular capsules based on a new design relying on both self-assembly and folding of oligomeric strands. We have designed an aromatic amide foldamer in which each monomer encodes three levels of information: a specific cavity size, recognition groups for guest binding, and a propensity to adopt a single or a double helical motif. Thus, a tetradecameric sequence based on four different monomers was encoded so that a wide double helical segment resulting from the hybridization of two strands creates a cavity in which guests, such as 1,10-decanediol, can be bound. Additionally two narrow single helical segments form end-caps and isolate the guest from the solvent. The design, synthesis, solid-state and solution-state characterization of duplex formation and guest binding are presented. |
| 语种 | 英语 |
| WOS记录号 | WOS:000271992100016 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/67617]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang, Hua |
| 作者单位 | 1.Univ Bordeaux, Inst Europeen Chim & Biol, CNRS, UMR5248 & UMS 3033, F-33607 Pessac, France 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Bao, Chunyan,Gan, Quan,Kauffmann, Brice,et al. A Self-Assembled Foldamer Capsule: Combining Single and Double Helical Segments in One Aromatic Amide Sequence[J]. CHEMISTRY-A EUROPEAN JOURNAL,2009,15(43):11530-11536. |
| APA | Bao, Chunyan,Gan, Quan,Kauffmann, Brice,Jiang, Hua,&Huc, Ivan.(2009).A Self-Assembled Foldamer Capsule: Combining Single and Double Helical Segments in One Aromatic Amide Sequence.CHEMISTRY-A EUROPEAN JOURNAL,15(43),11530-11536. |
| MLA | Bao, Chunyan,et al."A Self-Assembled Foldamer Capsule: Combining Single and Double Helical Segments in One Aromatic Amide Sequence".CHEMISTRY-A EUROPEAN JOURNAL 15.43(2009):11530-11536. |
入库方式： OAI收割
来源：化学研究所
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