Solvent size effect on the static and dynamic properties of polymer chains in athermal solvents
文献类型：期刊论文
| 作者 | Fu, Cui-Liu1; Ouyang, Wen-Ze1; Sun, Zhao-Yan1; An, Li-Jia1; Li, Hong-Fei1; Tong, Zhen2 |
| 刊名 | POLYMER
 |
| 出版日期 | 2009-10-09 |
| 卷号 | 50期号:21页码:5142-5148 |
| 关键词 | Solvent Size Effect Radius Of Gyration Diffusion Coefficient |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2009.09.010 |
| 英文摘要 | The static and dynamic properties of polymer chains in athermal solvents with different sizes are studied by molecular dynamics method. With increasing solvent size, the radius of gyration and the diffusion coefficient of the polymer decay fast until a critical solvent size is reached. For the polymer diffusion coefficients, this decay only depends on the solvent size; while for the radius of gyration of polymers, this decay depends on both solvent size and the length of the polymers. The increase of solvent size also makes the polymer tend to be thicker ellipsoid until a critical solvent size is reached. The static scaling exponent of the polymer also shows the solvent size dependence. Moreover, four regions are identified where the polymers show different dynamic behaviors according to the dynamic structure factors of the polymer. (C) 2009 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000270705700022 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/67765]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Zhao-Yan |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.S China Univ Technol, Res Inst Mat Sci, Guangzhou 510641, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fu, Cui-Liu,Ouyang, Wen-Ze,Sun, Zhao-Yan,et al. Solvent size effect on the static and dynamic properties of polymer chains in athermal solvents[J]. POLYMER,2009,50(21):5142-5148. |
| APA | Fu, Cui-Liu,Ouyang, Wen-Ze,Sun, Zhao-Yan,An, Li-Jia,Li, Hong-Fei,&Tong, Zhen.(2009).Solvent size effect on the static and dynamic properties of polymer chains in athermal solvents.POLYMER,50(21),5142-5148. |
| MLA | Fu, Cui-Liu,et al."Solvent size effect on the static and dynamic properties of polymer chains in athermal solvents".POLYMER 50.21(2009):5142-5148. |
入库方式： OAI收割
来源：化学研究所
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