Effect of Phase Behavior on the Ethenolysis of Ethyl Oleate in Compressed CO(2)
文献类型：期刊论文
| 作者 | Song, Jiyuan; Hou, Minqiang; Liu, Gang; Zhang, Jianling; Han, Buxing; Yang, Guanying |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY B
 |
| 出版日期 | 2009-03-05 |
| 卷号 | 113期号:9页码:2810-2814 |
| ISSN号 | 1520-6106 |
| DOI | 10.1021/jp810672e |
| 英文摘要 | How to enhance the reaction efficiency using greener methods is an important topic. In this work, the phase behavior of the reaction system of metathesis of ethyl oleate with ethene in compressed CO(2) was studied at 308.15 and 323.15 K using the Peng-Robinson equation of state. The effect of the phase behavior on the reaction rate and equilibrium conversion was studied. It was demonstrated that addition Of CO(2) in the reaction system could increase the reaction rate and equilibrium conversion considerably at suitable conditions where the solubility of the reactant in the vapor phase was low, while the solubility of the products was very high. However, at the condition where the solubility of the reactant and products were all high, the reaction rate was much slower. The mechanism for this interesting phenomenon was discussed in detail. |
| 语种 | 英语 |
| WOS记录号 | WOS:000263732700032 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/67829]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Han, Buxing |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Jiyuan,Hou, Minqiang,Liu, Gang,et al. Effect of Phase Behavior on the Ethenolysis of Ethyl Oleate in Compressed CO(2)[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2009,113(9):2810-2814. |
| APA | Song, Jiyuan,Hou, Minqiang,Liu, Gang,Zhang, Jianling,Han, Buxing,&Yang, Guanying.(2009).Effect of Phase Behavior on the Ethenolysis of Ethyl Oleate in Compressed CO(2).JOURNAL OF PHYSICAL CHEMISTRY B,113(9),2810-2814. |
| MLA | Song, Jiyuan,et al."Effect of Phase Behavior on the Ethenolysis of Ethyl Oleate in Compressed CO(2)".JOURNAL OF PHYSICAL CHEMISTRY B 113.9(2009):2810-2814. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。