Synthesis and Application of Thiadiazoloquinoxaline-Containing Chromophores as Dopants for Efficient Near-Infrared Organic Light-Emitting Diodes
文献类型：期刊论文
| 作者 | Qian, Gang1,2; Zhong, Ze1,2; Luo, Min1,2; Yu, Dengbin1; Zhang, Zhiqiang1; Ma, Dongge1; Wang, Zhi Yuan1,3 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY C
 |
| 出版日期 | 2009-01-29 |
| 卷号 | 113期号:4页码:1589-1595 |
| ISSN号 | 1932-7447 |
| DOI | 10.1021/jp809568a |
| 英文摘要 | A series of a donor-acceptor-donor type of near-infrared (NIR) fluorescent chromophores based on [1,2,5]thiadiazolo[3,4-g]quinoxaline (TQ) as an electron acceptor and triphenylamine as an electron donor are synthesized and characterized. By introducing pendent phenyl groups or changing the pi-conjugation length in the TQ core, we tuned tile energy levels of these chromophores, resulting in the NIR emission in a range from 784 to 868 nm. High thermal stability and glass transition temperatures allow these chromophores to be used as dopant emitters, which can be processed by vapor deposition for the fabrication of organic light-emitting diodes (OLEDs) having the multilayered structure of ITO/MoO(3)/NPB/Alq(3):dopant emitter/BCP/Alq(3)/LiF/Al. The electroluminescence spectra of the devices based on these new chromophores cover a range from 748 to 870 nm. With 2 wt % of dopant 1, the LED device shows an exclusive NIR emission at 752 nm with the external quantum efficiency (EQE) as high as 1.12% over a wide range of current density (e.g., around 200 mA cm(-2)). The radiance reaches the largest value of 2880 mW Sr(-1) m(-2) at an operating voltage of 15 V. |
| 语种 | 英语 |
| WOS记录号 | WOS:000262665600062 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/67903]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ma, Dongge |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Changchun 130022, Peoples R China 3.Carleton Univ, Dept Chem, Ottawa, ON K1S 5B6, Canada |
| 推荐引用方式 GB/T 7714 | Qian, Gang,Zhong, Ze,Luo, Min,et al. Synthesis and Application of Thiadiazoloquinoxaline-Containing Chromophores as Dopants for Efficient Near-Infrared Organic Light-Emitting Diodes[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2009,113(4):1589-1595. |
| APA | Qian, Gang.,Zhong, Ze.,Luo, Min.,Yu, Dengbin.,Zhang, Zhiqiang.,...&Wang, Zhi Yuan.(2009).Synthesis and Application of Thiadiazoloquinoxaline-Containing Chromophores as Dopants for Efficient Near-Infrared Organic Light-Emitting Diodes.JOURNAL OF PHYSICAL CHEMISTRY C,113(4),1589-1595. |
| MLA | Qian, Gang,et al."Synthesis and Application of Thiadiazoloquinoxaline-Containing Chromophores as Dopants for Efficient Near-Infrared Organic Light-Emitting Diodes".JOURNAL OF PHYSICAL CHEMISTRY C 113.4(2009):1589-1595. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。