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A Polythiophene Derivative with Dioctyloxyltriphenylamine-Vinylene Conjugated Side Chain: Synthesis, Hole Mobility, and Photovoltaic Property

文献类型:期刊论文

作者Wan, Meixiu1,2,3; Sang, Guangyi3; Zou, Yingping3; Tan, Songting1,2; Li, Yongfang3
刊名JOURNAL OF APPLIED POLYMER SCIENCE
出版日期2009-08-05
卷号113期号:3页码:1415-1421
关键词Conjugated Polymers Polythiophene Derivative Dioctyloxyl Triphenylamine-vinylene Side-chain Hole Mobility Polymer Solar Cell
ISSN号0021-8995
DOI10.1002/app.29921
英文摘要A new polythiophene derivative with dioctyloxyl triphenylamine-vinylene (DOTPAV) conjugated side-chain, DOTPAV-PT, was synthesized by the Stille coupling method and characterized by (1)H-NMR, (13)C-NMR, elemental analysis, get permeation chromatography, thermogravimetric analysis, UV-vis absorption spectroscopy, photoluminescence spectroscopy, and cyclic voltammetry. The polymer DOTPAV-PT is soluble in common organic solvents and possesses good thermal stability with 5%, weight loss temperature of 310 degrees C. The weight-average molecular weight of DOTPAV-PT is 8.0 K with a polydispersity index of 1.24. The hole mobility of the polymer determined from space-charge-limited Current model was 1.25 x 10(-4) cm(2) V(-1) s(-1). The bulk heterojunction polymer solar cell with the configuration of ITO/PEDOT : PSS/polymer : PCBM (1 : 1)/Ca/Al was fabricated, and the power conversion efficiency of the device was 0.16% under the illumination of AM1.5, 100 mW cm(-2). (C) 2009 Wiley Periodicals Inc. J Appl Polym Sci 113: 1415-1421, 2009
语种英语
WOS记录号WOS:000266891100007
出版者JOHN WILEY & SONS INC
源URL[http://ir.iccas.ac.cn/handle/121111/67967]  
专题中国科学院化学研究所
通讯作者Tan, Songting
作者单位1.Xiangtan Univ, Coll Chem, Xiangtan 411105, Peoples R China
2.Xiangtan Univ, Key Lab Polymer Mat & Applicat Technol Hunan Prov, Xiangtan 411105, Peoples R China
3.Chinese Acad Sci, CAS Key Lab Organ Solid, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Wan, Meixiu,Sang, Guangyi,Zou, Yingping,et al. A Polythiophene Derivative with Dioctyloxyltriphenylamine-Vinylene Conjugated Side Chain: Synthesis, Hole Mobility, and Photovoltaic Property[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2009,113(3):1415-1421.
APA Wan, Meixiu,Sang, Guangyi,Zou, Yingping,Tan, Songting,&Li, Yongfang.(2009).A Polythiophene Derivative with Dioctyloxyltriphenylamine-Vinylene Conjugated Side Chain: Synthesis, Hole Mobility, and Photovoltaic Property.JOURNAL OF APPLIED POLYMER SCIENCE,113(3),1415-1421.
MLA Wan, Meixiu,et al."A Polythiophene Derivative with Dioctyloxyltriphenylamine-Vinylene Conjugated Side Chain: Synthesis, Hole Mobility, and Photovoltaic Property".JOURNAL OF APPLIED POLYMER SCIENCE 113.3(2009):1415-1421.

入库方式: OAI收割

来源:化学研究所

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