Kinetic study of the reaction of chlorine atoms with 3-methyl-3-buten-1-ol
文献类型：期刊论文
| 作者 | Wang Lei; Ge MaoFa; Wang WeiGang |
| 刊名 | CHINESE SCIENCE BULLETIN
 |
| 出版日期 | 2009-10-01 |
| 卷号 | 54期号:20页码:3808-3812 |
| 关键词 | Atmosphereic Chemistry Chloride Atoms Unsaturated Alcohols Gas-phase Reaction Kinetics |
| ISSN号 | 1001-6538 |
| DOI | 10.1007/s11434-009-0439-1 |
| 英文摘要 | The reaction of a typical unsaturated alcohol, 3-methyl-3-buten-1-ol (MBO331), with Cl atoms, was investigated for the first time. The reaction was investigated using discharged flow-tube coupled with electron impact mass spectrometer. The experiments were performed over the temperature range of 248 K-298 K and at pressure of 1 torr in He as the bath gas. The obtained kinetic data were used to derive the Arrhenius expression: k(1) = (3.47 +/- 1.21) x 10(-11) exp[(599 +/- 69)/T] cm(3) molecule(-1) s(-1). Finally, atmospheric lifetimes of the MBO331 with respect to OH radicals, NO(3) radicals and Cl atoms have been calculated and the atmospheric implications are considered briefly. |
| 语种 | 英语 |
| WOS记录号 | WOS:000271175500033 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/67975]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ge MaoFa |
| 作者单位 | Chinese Acad Sci, Inst Chem, BNLMS, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang Lei,Ge MaoFa,Wang WeiGang. Kinetic study of the reaction of chlorine atoms with 3-methyl-3-buten-1-ol[J]. CHINESE SCIENCE BULLETIN,2009,54(20):3808-3812. |
| APA | Wang Lei,Ge MaoFa,&Wang WeiGang.(2009).Kinetic study of the reaction of chlorine atoms with 3-methyl-3-buten-1-ol.CHINESE SCIENCE BULLETIN,54(20),3808-3812. |
| MLA | Wang Lei,et al."Kinetic study of the reaction of chlorine atoms with 3-methyl-3-buten-1-ol".CHINESE SCIENCE BULLETIN 54.20(2009):3808-3812. |
入库方式： OAI收割
来源：化学研究所
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