Effect of Electrostatic Interactions on Metallophthalocyanine Single Molecular Arrays with n-Octadecyl Mercaptan Templates
文献类型：期刊论文
| 作者 | Kong, Xianghua2,3; Deng, Ke1; Yang, Yanlian1; Lei, Shengbin1; Wang, Chen1 |
| 刊名 | JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
 |
| 出版日期 | 2009-02-01 |
| 卷号 | 9期号:2页码:1152-1155 |
| 关键词 | Scanning Tunneling Microscopy Single Molecular Array Metallophthalocyanine Density Functional Theory |
| ISSN号 | 1533-4880 |
| DOI | 10.1166/jnn.2009.C108 |
| 英文摘要 | By changing central metal ions or by tuning the length of substituted alkyl chains, metallophthalocyanines or their derivatives exhibit various assembling behaviors when co-adsorbed with n-octadecyl mercaptan on highly oriented pyrolytic graphite surfaces. Repeated scanning tunneling microscopy experiments demonstrate that planar or short alkyl chain substituted MPcs could form single molecular arrays while phase separation occurred when non-planar or longer alkyl chain substituted MPcs were co-adsorbed with C18SH templates. The experimental results combined with the density functional theory calculations reveal that intermolecular electrostatic and van der Waals interactions play essential roles in the formation of single molecular arrays. |
| 语种 | 英语 |
| WOS记录号 | WOS:000263653300108 |
| 出版者 | AMER SCIENTIFIC PUBLISHERS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68029]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Chen |
| 作者单位 | 1.Natl Ctr Nanosci & Technol, Beijing 100080, Peoples R China 2.CAS, Inst Chem, Beijing 100080, Peoples R China 3.CAS, Grad Sch, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kong, Xianghua,Deng, Ke,Yang, Yanlian,et al. Effect of Electrostatic Interactions on Metallophthalocyanine Single Molecular Arrays with n-Octadecyl Mercaptan Templates[J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,2009,9(2):1152-1155. |
| APA | Kong, Xianghua,Deng, Ke,Yang, Yanlian,Lei, Shengbin,&Wang, Chen.(2009).Effect of Electrostatic Interactions on Metallophthalocyanine Single Molecular Arrays with n-Octadecyl Mercaptan Templates.JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,9(2),1152-1155. |
| MLA | Kong, Xianghua,et al."Effect of Electrostatic Interactions on Metallophthalocyanine Single Molecular Arrays with n-Octadecyl Mercaptan Templates".JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY 9.2(2009):1152-1155. |
入库方式： OAI收割
来源：化学研究所
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