Enhancing the selectivity of the hydrogenation of naphthalene to tetralin by high temperature water
文献类型：期刊论文
| 作者 | Cheng, Yan1; Fan, Honglei1; Wu, Suxiang1; Wang, Qian1; Guo, Jin1,2; Gao, Liang3; Zong, Baoning3; Han, Buxing1 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2009 |
| 卷号 | 11期号:7页码:1061-1065 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/b904305e |
| 英文摘要 | Enhancing selectivity and an efficient use of feedstocks in chemical reactions using greener methods is an important aspect of green chemistry. In this work, we conducted the hydrogenation of naphthalene to produce tetralin catalyzed by a cheap Fe-Mo based catalyst with and without high temperature water (HTW). The effects of various factors on the reaction, such as density of water, reaction temperature, reaction time and amounts of catalyst, were investigated. It was demonstrated that the addition of water could increase the yield of tetralin and suppress formation of coke effectively. The reaction in the presence of D(2)O indicated that H/D exchange occurred during the reaction process. |
| 语种 | 英语 |
| WOS记录号 | WOS:000267727800027 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68155]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Cheng, Yan |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.China Univ Min & Technol, Beijing 100190, Peoples R China 3.Res Inst Petr Proc, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, Yan,Fan, Honglei,Wu, Suxiang,et al. Enhancing the selectivity of the hydrogenation of naphthalene to tetralin by high temperature water[J]. GREEN CHEMISTRY,2009,11(7):1061-1065. |
| APA | Cheng, Yan.,Fan, Honglei.,Wu, Suxiang.,Wang, Qian.,Guo, Jin.,...&Han, Buxing.(2009).Enhancing the selectivity of the hydrogenation of naphthalene to tetralin by high temperature water.GREEN CHEMISTRY,11(7),1061-1065. |
| MLA | Cheng, Yan,et al."Enhancing the selectivity of the hydrogenation of naphthalene to tetralin by high temperature water".GREEN CHEMISTRY 11.7(2009):1061-1065. |
入库方式： OAI收割
来源：化学研究所
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