Influence of Intermolecular N-H center dot center dot center dot pi Interactions on Molecular Packing and Field-Effect Performance of Organic Semiconductors
文献类型：期刊论文
| 作者 | Zhao, Huaping2; Jiang, Lang2,3; Dong, Huanli2,3; Li, Hongxiang1; Hu, Wenping2; Ong, Beng S.4 |
| 刊名 | CHEMPHYSCHEM
 |
| 出版日期 | 2009-09-09 |
| 卷号 | 10期号:13页码:2345-2348 |
| 关键词 | Charge Transport Nitrogen Heterocycles Pi Interactions Semiconductors Solid-state Structures |
| ISSN号 | 1439-4235 |
| DOI | 10.1002/cphc.200900249 |
| 英文摘要 | Charge transport in organic semiconductors is strongly dependent on their molecular packing modes in the solid state. Therefore, understanding the relationship between molecular packing and charge transport is imperative both experimentally and theoretically. However, so far, the fundamental effects of solid-state packing and molecular interactions (e.g. N-H center dot center dot center dot pi) on charge transport need further elucidation. Herein, indolo[3,2-b]carbazole (ICZ) and a derivative thereof are used as examples to approach this scientific target. An interesting insight obtained thereby is that N-H center dot center dot center dot pi interactions among ICZ molecules facilitate charge transport for higher mobility. Subtle changes in the of N-H center dot center dot center dot pi interactions can significantly influence both the molecular packing and the charge-transport properties. Therefore, a method for exploiting intermolecular N-H center dot center dot center dot pi interactions would yield novel molecular systems with designable characteristics. |
| 语种 | 英语 |
| WOS记录号 | WOS:000269979600026 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68157]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Hongxiang |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China 4.Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore |
| 推荐引用方式 GB/T 7714 | Zhao, Huaping,Jiang, Lang,Dong, Huanli,et al. Influence of Intermolecular N-H center dot center dot center dot pi Interactions on Molecular Packing and Field-Effect Performance of Organic Semiconductors[J]. CHEMPHYSCHEM,2009,10(13):2345-2348. |
| APA | Zhao, Huaping,Jiang, Lang,Dong, Huanli,Li, Hongxiang,Hu, Wenping,&Ong, Beng S..(2009).Influence of Intermolecular N-H center dot center dot center dot pi Interactions on Molecular Packing and Field-Effect Performance of Organic Semiconductors.CHEMPHYSCHEM,10(13),2345-2348. |
| MLA | Zhao, Huaping,et al."Influence of Intermolecular N-H center dot center dot center dot pi Interactions on Molecular Packing and Field-Effect Performance of Organic Semiconductors".CHEMPHYSCHEM 10.13(2009):2345-2348. |
入库方式： OAI收割
来源：化学研究所
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