Electroluminescent Fluorene-Based Alternating Polymers Bearing Triarylamine or Carbazole Moieties in the Main Chain: Synthesis and Properties
文献类型：期刊论文
| 作者 | Zou, Yingping1,2; Zhou, Yi2; Wu, Guanglong2; Li, Yongfang2; Pan, Chunyue1 |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2009-01-15 |
| 卷号 | 111期号:2页码:978-987 |
| 关键词 | Triphenylamine Carbazole Suzuki Polymerization Reaction Photophysical Properties Electroluminescence |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.29156 |
| 英文摘要 | Two soluble conjugated polyfluorenes, poly {9,9-dioctylfluorene-2,7-diyl-co-4,4'-bis[2-(4-phenyl)-2-cyanovinyl] triphenylamine} (PF-BCT) and poly {9,9-dioctylfluorene-2,7-diyl-co-3,6-bis[2-(4-phenyl)-2-cyanovinyl]-9-octyl carbazole}(PF-BCC), have been synthesized from 2,7-dibromo-9,9-dioctylfluorene and 4,4'-bis[2-(4-bromophenyl)-2-cyanovinyl]triphenylamine or 3,6-bis[2-(4-bromophenyl)-2-cyanovinyl]-9-octyl carbazole comonomers through a Suzuki polymerization reaction. The copolymers are characterized by gel permeation chromatography, elemental analysis, thermogravimetric analysis. The polymers have good thermal stability with 5 wt % loss temperatures of more than 380 degrees C. Cyclic voltammetry measurements show that the polymers present goad electron and hole-injection abilities. PF-BCC possesses higher oxidization potential than that of PF-BCT, which indicates that PF-BCT has better hole injection ability. The photophysical properties of the polymers are investigated in both solutions and spinning-coated films. Compared to that of PF-BCC, the absorption and emission peaks of PF-BCT bathochromic shift in the solid film or solution states. Single layer light-emitting devices have been fabricated in the ITO/PEDOT: PSS/polymer/Ca/Al configuration. The electroluminescence (EL) device based on PF-BCT shows yellow emission with the current efficiency of 0.21 cd/A, while PF-BCC shows greenish yellow emission with the current efficiency of 0.08 cd/A. In addition, to improve the electroluminescence of PF-BCC, a, PVK layer is introduced, the brightness and efficiency get improved to 700 cd/m(2) and 0.12 cd/A, respectively. (C) 2008 Wiley Periodicals, Inc. J Appl Polym Sci 111: 978-987, 2009 |
| 语种 | 英语 |
| WOS记录号 | WOS:000261152500070 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68185]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zou, Yingping |
| 作者单位 | 1.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China 2.Chinese Acad Sci, CAS Key Lab Organ Solids, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zou, Yingping,Zhou, Yi,Wu, Guanglong,et al. Electroluminescent Fluorene-Based Alternating Polymers Bearing Triarylamine or Carbazole Moieties in the Main Chain: Synthesis and Properties[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2009,111(2):978-987. |
| APA | Zou, Yingping,Zhou, Yi,Wu, Guanglong,Li, Yongfang,&Pan, Chunyue.(2009).Electroluminescent Fluorene-Based Alternating Polymers Bearing Triarylamine or Carbazole Moieties in the Main Chain: Synthesis and Properties.JOURNAL OF APPLIED POLYMER SCIENCE,111(2),978-987. |
| MLA | Zou, Yingping,et al."Electroluminescent Fluorene-Based Alternating Polymers Bearing Triarylamine or Carbazole Moieties in the Main Chain: Synthesis and Properties".JOURNAL OF APPLIED POLYMER SCIENCE 111.2(2009):978-987. |
入库方式： OAI收割
来源：化学研究所
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