SOLUTION COPOLYMERIZATION OF ACRYLONITRILE WITH 1-ALLYL-3-METHYL-IMIDAZOLIUM
文献类型：期刊论文
| 作者 | Zhang Guibao; Liu Xiaohui; Li Baixiang; Bai Yungang |
| 刊名 | ACTA POLYMERICA SINICA
 |
| 出版日期 | 2009-03-20 |
| 期号 | 3页码:216-221 |
| 关键词 | 1-allyl-3-methyl-imidazolium Chloride Ionic Liquid Comonomer Acrylonitrile Radical Copolymerization Carbon Fiber |
| ISSN号 | 1000-3304 |
| 英文摘要 | Ionic liquid conionomer 1-allyl-3-methyl-imidazolium chloride ([AMIM]Cl) was first used to copolymerize with acrylonitrile (AN) successfully in various conditions. This was achieved by using azobisisobutyronitrile as the initiator and dimethyl sulfoxide as the solvent. The kinetics of the above copolymerization was studied. The values of monomer apparent reactivity ratios were calculated. The apparent reactivity ratios of AN and [AMIM]Cl are as follows: r(AN) =8.11 r([AMIM]Cl) = 0. The copolymers were obtained with high molecular weights and high hydrophilicity.[AMIM]Cl has dual functions in the dope:the part in the molecular chains can mediate the hydrophilicity and spinnicity of the copolymers, and the other part In the solution can decrease the viscosity of the dope. The copolymers were characterized by (1)H-NMR, GPC, DSC and TGA. The copolymers may be potentially useful in preparing precursor fibers and carbon fibers. |
| 语种 | 英语 |
| WOS记录号 | WOS:000264545600004 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68257]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang Guibao |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang Guibao,Liu Xiaohui,Li Baixiang,et al. SOLUTION COPOLYMERIZATION OF ACRYLONITRILE WITH 1-ALLYL-3-METHYL-IMIDAZOLIUM[J]. ACTA POLYMERICA SINICA,2009(3):216-221. |
| APA | Zhang Guibao,Liu Xiaohui,Li Baixiang,&Bai Yungang.(2009).SOLUTION COPOLYMERIZATION OF ACRYLONITRILE WITH 1-ALLYL-3-METHYL-IMIDAZOLIUM.ACTA POLYMERICA SINICA(3),216-221. |
| MLA | Zhang Guibao,et al."SOLUTION COPOLYMERIZATION OF ACRYLONITRILE WITH 1-ALLYL-3-METHYL-IMIDAZOLIUM".ACTA POLYMERICA SINICA .3(2009):216-221. |
入库方式： OAI收割
来源：化学研究所
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