Synthesis and characterization of three ionic pairs of Fe(II) and Co(II) complexes with tridentate salicylideneglycine
文献类型:期刊论文
作者 | Han, Jing1; Xing, Yong Heng1; Bai, Feng Ying1; Zhang, Xing Jing1; Zeng, Xiao Qing2; Ge, Mao Fa2 |
刊名 | JOURNAL OF COORDINATION CHEMISTRY
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出版日期 | 2009 |
卷号 | 62期号:16页码:2719-2727 |
关键词 | Complexes Salicylideneglycine Ligand Crystal Structure Hydrogen Bonds |
ISSN号 | 0095-8972 |
DOI | 10.1080/00958970902902705 |
英文摘要 | Three new transition metal complexes, [FeII(H2O)6][(C9H7NO3)2FeII] center dot H2O (1), H[K(H2O)3][(C9H7NO3)2CoII] center dot H2O (2), and [CoII(H2O)6][(C9H7NO3)2CoII] center dot H2O (3), with salicylideneglycine have been synthesized and characterized by elemental analysis, IR spectra, UV-Vis spectroscopy, and X-ray crystallography. The structure analyses indicate that the tridentate salicylideneglycine binds through aliphatic nitrogen, phenoxy, and carboxylic oxygen in the anion. There are many inter- and intra-molecular hydrogen bonds among lattice water, the anion, and the cation to form a 3-D network. The thermogravimetric analyses and the quantum chemistry calculations of compounds 1, 2, and 3 are also discussed. |
语种 | 英语 |
WOS记录号 | WOS:000268032900017 |
出版者 | TAYLOR & FRANCIS LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/68283] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Xing, Yong Heng |
作者单位 | 1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Han, Jing,Xing, Yong Heng,Bai, Feng Ying,et al. Synthesis and characterization of three ionic pairs of Fe(II) and Co(II) complexes with tridentate salicylideneglycine[J]. JOURNAL OF COORDINATION CHEMISTRY,2009,62(16):2719-2727. |
APA | Han, Jing,Xing, Yong Heng,Bai, Feng Ying,Zhang, Xing Jing,Zeng, Xiao Qing,&Ge, Mao Fa.(2009).Synthesis and characterization of three ionic pairs of Fe(II) and Co(II) complexes with tridentate salicylideneglycine.JOURNAL OF COORDINATION CHEMISTRY,62(16),2719-2727. |
MLA | Han, Jing,et al."Synthesis and characterization of three ionic pairs of Fe(II) and Co(II) complexes with tridentate salicylideneglycine".JOURNAL OF COORDINATION CHEMISTRY 62.16(2009):2719-2727. |
入库方式: OAI收割
来源:化学研究所
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