A highly alpha-regioselective In(OTf)(3)-catalyzed N-nucleophilic substitution of cyclic Baylis-Hillman adducts with aromatic amines
文献类型：期刊论文
| 作者 | Liu, Yu-Liang; Liu, Li; Wang, Dong; Chen, Yong-Jun |
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2009-04-25 |
| 卷号 | 65期号:17页码:3473-3479 |
| 关键词 | Catalytic Allylic Amination Cyclic B-h Adduct Aromatic Amine Allylic Rearrangement Alpha-regioselectivity |
| ISSN号 | 0040-4020 |
| DOI | 10.1016/j.tet.2009.02.048 |
| 英文摘要 | The highly alpha-regioselective N-nucleophilic substitution of B-H adducts bearing five (1a-f) or six-membered ring (Sa-e) moieties with aromatic amines (2a-e) was developed under the catalysis of In(OTf)(3) (10 mol%). During the reaction the allylic rearrangement from gamma-product to alpha-product occurred, resulting in thermodynamically stable alpha-product predominately. (C) 2009 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000265175100018 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68291]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Li |
| 作者单位 | Chinese Acad Sci, Inst Chem, Biol Chem Lab, Beijing Natl Lab BNLMS, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Yu-Liang,Liu, Li,Wang, Dong,et al. A highly alpha-regioselective In(OTf)(3)-catalyzed N-nucleophilic substitution of cyclic Baylis-Hillman adducts with aromatic amines[J]. TETRAHEDRON,2009,65(17):3473-3479. |
| APA | Liu, Yu-Liang,Liu, Li,Wang, Dong,&Chen, Yong-Jun.(2009).A highly alpha-regioselective In(OTf)(3)-catalyzed N-nucleophilic substitution of cyclic Baylis-Hillman adducts with aromatic amines.TETRAHEDRON,65(17),3473-3479. |
| MLA | Liu, Yu-Liang,et al."A highly alpha-regioselective In(OTf)(3)-catalyzed N-nucleophilic substitution of cyclic Baylis-Hillman adducts with aromatic amines".TETRAHEDRON 65.17(2009):3473-3479. |
入库方式： OAI收割
来源：化学研究所
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