Macrocycle-Terminated Core-Cross-Linked Star Polymers: Synthesis and Characterization
文献类型：期刊论文
| 作者 | Peng, Yun1; Liu, Hewen1; Zhang, Xingyuan1; Liu, Shiyong1; Li, Yuesheng2 |
| 刊名 | MACROMOLECULES
 |
| 出版日期 | 2009-09-08 |
| 卷号 | 42期号:17页码:6457-6462 |
| ISSN号 | 0024-9297 |
| DOI | 10.1021/ma901041x |
| 英文摘要 | We have synthesized macrocyclic polystyrene- (PS-) terminated PS star polymers via a core-cross-linking approach in this work. A tadpole-shaped macrocyclic PS-linear-PS copolymer was synthesized at first via click chemistry and ATRP polymerization method. The "living" ATRP initiating chain-ends of the tadpole-shaped copolymers were linked together via ATRP polymerization with divinylbenzene to form a core-cross-linked macrocyclic star polymer. The number of arms attached to the macrocyclic star polymers was measured with NMR. and absolute molecular weights with gel permeation chromatography (GPC) with multiangle laser light scattering detector. These macrocyclic star polymers had a highly cross-linked core and many radiating arms. The shorter tadpole-shaped precursors caused core-cross-linked star polymers with higher molecular weights and more arm numbers. The macrocycle-terminated core-cross-linked star polymers showed two glass transition temperatures, one arising from the linear branches and another from the macrocycles. |
| 语种 | 英语 |
| WOS记录号 | WOS:000269635900017 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68327]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Hewen |
| 作者单位 | 1.Univ Sci & Technol China, Dept Polymer Sci & Engn, CAS Key Lab Soft Matter Chem, Hefei 230026, Anhui, Peoples R China 2.State Key Lab Polymer Phys & Chem, Changchun, Peoples R China |
| 推荐引用方式 GB/T 7714 | Peng, Yun,Liu, Hewen,Zhang, Xingyuan,et al. Macrocycle-Terminated Core-Cross-Linked Star Polymers: Synthesis and Characterization[J]. MACROMOLECULES,2009,42(17):6457-6462. |
| APA | Peng, Yun,Liu, Hewen,Zhang, Xingyuan,Liu, Shiyong,&Li, Yuesheng.(2009).Macrocycle-Terminated Core-Cross-Linked Star Polymers: Synthesis and Characterization.MACROMOLECULES,42(17),6457-6462. |
| MLA | Peng, Yun,et al."Macrocycle-Terminated Core-Cross-Linked Star Polymers: Synthesis and Characterization".MACROMOLECULES 42.17(2009):6457-6462. |
入库方式： OAI收割
来源：化学研究所
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