Steric hindrance-dependent rational design and synthesis of three new Keggin-based supramolecular networks
文献类型：期刊论文
| 作者 | Zhang, Xiao1,2; Yi, Zhihui3; Zhao, Liyan1,2; Chen, Qian1,2; Gu, Xianmo1,2; Xu, Jiqing4,5; Wang, Xiaolin1,2; Yang, Chao1,2; Xu, Xianzhu1,2; Xia, Wujiong1,2 |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2009 |
| 期号 | 42页码:9198-9206 |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/b906313g |
| 英文摘要 | Three supramolecular architectures based on alpha-Keggin-type polyoxometalates have been synthesized hydrothermally, and their structures have been characterized by elemental analyses, infrared (IR) spectroscopy, X-ray photoelectron spectroscopy (XPS) and single crystal X-ray diffraction structure analyses. [Ni(enMe)(2)(H(2)O)(2)](2)[Ni(enMe)(2)PW(9)(VI)W(3)(V)O(40)]center dot H(2)O (1) (enMe = 1,2'-propanediamine) exhibits a novel 2-D supramolecular sinusoidal layer through the interactions between transition metal complexes and 1-D covalent chains which are constructed from alpha-Keggin units bridged by transition metal complexes. [Ni(enMe)(2)](4){[Ni(enMe)(2)][Ni(enMe)(2)(H(2)O)AsW(6)(VI)W(4)(V)V(4)(IV)O(42)](2)}center dot 6H(2)O (2), representing a 3-D supramolecular framework with 1-D channels, contains the first example of a tungstate dimer with inorganic-organic composite surfaces built up from [Ni(enMe)(2)](2+) cation bridges and bi-capped alpha-Keggin polyoxometalate building blocks supporting the transition metal complex. [Ni(enMe)(2)](4){[Ni(enMe)(2)][Ni(enMe)(2)(H(2)O)AsMo(4)(VI)Mo(4)(V)V(8)(IV)O(44)](2)}center dot 8H(2)O (3), showing a 3-D supramolecular framework with 1-D channels, contains the first example of a molybdoarsenate dimer formed by [Ni(enMe)(2)](2+) cations bridging two neighboring tetra-capped alpha-Keggin-based molybdates that support the transition metal complex [Ni(enMe)(2)H(2)O]. The topological networks of the supramolecular frameworks of 2 and 3 are analogous. Crystal structural analysis reveals that the dimensionality and the organization of polyoxometalate building units in the solid state can be tuned by the steric hindrances of the polyanions. Both 2 and 3 exhibit intensive photoluminescence. |
| 语种 | 英语 |
| WOS记录号 | WOS:000270973800018 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68413]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xia, Wujiong |
| 作者单位 | 1.Harbin Inst Technol, SKLUWRE, Harbin 150080, Heilongjiang, Peoples R China 2.Harbin Inst Technol, Acad Fundamental & Interdisciplinary Sci, Harbin 150080, Heilongjiang, Peoples R China 3.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 4.Jilin Univ, Coll Chem, Changchun 130023, Jilin, Peoples R China 5.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Jilin, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Xiao,Yi, Zhihui,Zhao, Liyan,et al. Steric hindrance-dependent rational design and synthesis of three new Keggin-based supramolecular networks[J]. DALTON TRANSACTIONS,2009(42):9198-9206. |
| APA | Zhang, Xiao.,Yi, Zhihui.,Zhao, Liyan.,Chen, Qian.,Gu, Xianmo.,...&Xia, Wujiong.(2009).Steric hindrance-dependent rational design and synthesis of three new Keggin-based supramolecular networks.DALTON TRANSACTIONS(42),9198-9206. |
| MLA | Zhang, Xiao,et al."Steric hindrance-dependent rational design and synthesis of three new Keggin-based supramolecular networks".DALTON TRANSACTIONS .42(2009):9198-9206. |
入库方式： OAI收割
来源：化学研究所
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