Starburst substituted hexaazatriphenylene compounds: synthesis, photophysical and electrochemical properties
文献类型：期刊论文
| 作者 | Gao, Baoxiang1; Liu, Yueling1; Geng, Yanhou2; Cheng, Yanxiang2; Wang, Lixiang2; Jing, Xiabin2; Wang, Fosong2 |
| 刊名 | TETRAHEDRON LETTERS
 |
| 出版日期 | 2009-04-08 |
| 卷号 | 50期号:14页码:1649-1652 |
| 关键词 | Hexaazatriphenylene Bandgap Fluorescence Electrochemical |
| ISSN号 | 0040-4039 |
| DOI | 10.1016/j.tetlet.2009.01.126 |
| 英文摘要 | Starburst-substituted hexaazatriphenylene Compounds have been designed and synthesized by introducing various peripheral aryl substituents to the central heterocyclic core. The effects of various substituent groups on the photophysical and electrochemical properties of the substituted hexaazatriphenylene have been investigated. Significant red-shifts of the absorption peak (from 413 nm to 530 nm) and emission peak (from 432 nm to 700 nm) were observed when the electron-donating ability of the aryl substituents was increased, corresponding to a decrease in the band gap from 2.90 eV to 2.05 eV. Introducing bulky substituents with weak electron-donating ability enhances the fluorescence quantum yield from 23% to 87%. In contrast, incorporating aryl substituents with strong electron-donating ability decreases the fluorescence quantum yield. Also, due to the extended conjugation between the aryl substituents and the hexaazatriphenylene core, the reduction potentials of the compounds were reduced and the LUMO levels were thus increased. (C) 2009 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000264210100038 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68437]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gao, Baoxiang |
| 作者单位 | 1.Hebei Univ, Coll Chem & Environm Sci, Minist Educ, Key Lab Med Chem & Mol Diag, Baoding 071002, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Baoxiang,Liu, Yueling,Geng, Yanhou,et al. Starburst substituted hexaazatriphenylene compounds: synthesis, photophysical and electrochemical properties[J]. TETRAHEDRON LETTERS,2009,50(14):1649-1652. |
| APA | Gao, Baoxiang.,Liu, Yueling.,Geng, Yanhou.,Cheng, Yanxiang.,Wang, Lixiang.,...&Wang, Fosong.(2009).Starburst substituted hexaazatriphenylene compounds: synthesis, photophysical and electrochemical properties.TETRAHEDRON LETTERS,50(14),1649-1652. |
| MLA | Gao, Baoxiang,et al."Starburst substituted hexaazatriphenylene compounds: synthesis, photophysical and electrochemical properties".TETRAHEDRON LETTERS 50.14(2009):1649-1652. |
入库方式： OAI收割
来源：化学研究所
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