N-(2-Benzimidazolylquinolin-8-yl)benzamidate Half-Titanocene Chlorides: Synthesis, Characterization and Their Catalytic Behavior Toward Ethylene Polymerization
文献类型：期刊论文
| 作者 | Liu, Shaofeng1,2; Yi, Jianjun3; Zuo, Weiwei1,2; Wang, Kefeng1,2; Wang, Deligeer1,2,4; Sun, Wen-Hua1,2
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| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
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| 出版日期 | 2009-06-15 |
| 卷号 | 47期号:12页码:3154-3169 |
| 关键词 | Cationic Polymerization Copolymerization Metal-organic Catalysts N-(2-benzimidazolyquinoliN-8-yl)Benzamide Polyethylene |
| ISSN号 | 0887-624X |
| DOI | 10.1002/pola.23413 |
| 英文摘要 | A series of N-(2-benzimidazolyquinolin-8-yl)benzamidate half-titanocene chlorides, Cp'TiLCl (C1-C8 Cp' = C(5)H(5), MeC(5)H(4), or C(5)Me(5); L = N-(benzimidazolyquinolin-8-yl)benzamides)), was synthesized by the KCl elimination reaction of half-titanocene trichlorides with the correspondent potassium N-(2-benzimidazolyquinolin-8-yl)benzamide. These half-titanocene complexes were fully characterized by elemental and NMR analyses, and the molecular structures of complexes C2 and C8 were determined by the single-crystal X-ray diffraction. The high stability of the pentamethylcyclopentadienyl complex (C8) was evident by no decomposing nature of its solution in air for one week. The oxo-bridged dimeric complex (C9) was isolated from the solution of the corresponding cyclopentadienyl complex (C3) solution in air. Complexes C1-C8 exhibited good to high catalytic activities toward ethylene polymerization and ethylene/alpha-olefin copolymerization in the presence of methylaluminoxane (MAO) cocatalyst. In the typical catalytic system of C1/MAO, the polymerization productivities were enhanced with either elevating reaction temperature or increasing the ratio of MAO to titanium precursor. In general, it was observed that higher the catalytic activity of the catalytic system lower the molecular weight of polyethylene. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 3154-3169, 2009 |
| 语种 | 英语 |
| WOS记录号 | WOS:000266780000018 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/68491]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Wen-Hua |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 3.PetroChina Ltd, Petrochem Res Inst, Beijing 100083, Peoples R China 4.Inner Mongolia Normal Univ, Dept Chem, Hohhot 010022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Shaofeng,Yi, Jianjun,Zuo, Weiwei,et al. N-(2-Benzimidazolylquinolin-8-yl)benzamidate Half-Titanocene Chlorides: Synthesis, Characterization and Their Catalytic Behavior Toward Ethylene Polymerization[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2009,47(12):3154-3169. |
| APA | Liu, Shaofeng,Yi, Jianjun,Zuo, Weiwei,Wang, Kefeng,Wang, Deligeer,&Sun, Wen-Hua.(2009).N-(2-Benzimidazolylquinolin-8-yl)benzamidate Half-Titanocene Chlorides: Synthesis, Characterization and Their Catalytic Behavior Toward Ethylene Polymerization.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,47(12),3154-3169. |
| MLA | Liu, Shaofeng,et al."N-(2-Benzimidazolylquinolin-8-yl)benzamidate Half-Titanocene Chlorides: Synthesis, Characterization and Their Catalytic Behavior Toward Ethylene Polymerization".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 47.12(2009):3154-3169. |
入库方式： OAI收割
来源：化学研究所
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