Dendritic Effect on Supramolecular Self-Assembly: Organogels with Strong Fluorescence Emission Induced by Aggregation
文献类型:期刊论文
作者 | Chen, Yulan1; Lv, Yuxia2; Han, Yang1; Zhu, Bo1; Zhang, Fan1; Bo, Zhishan1; Liu, Chen-Yang2 |
刊名 | LANGMUIR
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出版日期 | 2009-08-04 |
卷号 | 25期号:15页码:8548-8555 |
ISSN号 | 0743-7463 |
DOI | 10.1021/la803436h |
英文摘要 | A novel class of dumbbell-shaped dendritic molecules with a p-terphenylene core was synthesized, and their self-assembling properties were investigated. The incorporation of bulky dendritic wedges to the central stiff aromatic scaffolds could finely time their solubility in many organic solvents. Unlike the self-assembly behavior of p-terphenylen-1,4 ''-ylenebis(dodecanamide), the p-terphenylene cored different generation dendritic molecules could form gels in several kinds of organic solvents through a cooperative effect of the pi-pi stacking, hydrogen-bonding, and van der Waals forces. Interestingly, significant fluorescence enhancement was observed after gelation. Extensive investigations with atomic force microscopy (AFM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), rheological measurements, UV-vis absorption spectroscopy, FT-IR spectroscopy, (1)H NMR, and X-ray powder diffraction (XRD) revealed that these dendritic molecules self-assembled into elastically interpenetrating one-dimensional nanostructures in organogels. |
语种 | 英语 |
WOS记录号 | WOS:000268231500035 |
出版者 | AMER CHEMICAL SOC |
源URL | [http://ir.iccas.ac.cn/handle/121111/68503] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Bo, Zhishan |
作者单位 | 1.Chinese Acad Sci, BNLMS, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Key Lab Engn Plast, Inst Chem, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Yulan,Lv, Yuxia,Han, Yang,et al. Dendritic Effect on Supramolecular Self-Assembly: Organogels with Strong Fluorescence Emission Induced by Aggregation[J]. LANGMUIR,2009,25(15):8548-8555. |
APA | Chen, Yulan.,Lv, Yuxia.,Han, Yang.,Zhu, Bo.,Zhang, Fan.,...&Liu, Chen-Yang.(2009).Dendritic Effect on Supramolecular Self-Assembly: Organogels with Strong Fluorescence Emission Induced by Aggregation.LANGMUIR,25(15),8548-8555. |
MLA | Chen, Yulan,et al."Dendritic Effect on Supramolecular Self-Assembly: Organogels with Strong Fluorescence Emission Induced by Aggregation".LANGMUIR 25.15(2009):8548-8555. |
入库方式: OAI收割
来源:化学研究所
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